Matches in SemOpenAlex for { <https://semopenalex.org/work/W1971066365> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W1971066365 endingPage "3640" @default.
- W1971066365 startingPage "3637" @default.
- W1971066365 abstract "The nitrosyl complex H[TcNOCl4] reacts with the tridentate ligand bis[(2-diphenylphosphino)propyl]amine (PNPpr) to yield a mixture of the mer or fac isomers of [TcCl2(NO)(PNPpr)]. In acetonitrile, where the ligand is freely soluble, reaction occurs at room temperature to yield mostly the mer isomer with the linear nitrosyl ligand cis to the amine ligand; and the phosphine ligands arranged in a mutually trans orientation. The reaction in methanol requires reflux to dissolve the lipophilic ligand and generates the fac isomer of [TcCl2(NO)(PNPpr)] as the major product, with the tridentate ligand in a facial arrangement, leaving the chlorides and nitrosyl ligand in the remaining facial sites. The steric bulk of the tridentate ligand’s diphenylphophino-moieties results in a significant distortion from octahedral geometry, with the P–Tc–P bond angle expanded to 99.48(4)°.The infrared spectra display absorptions from these nitrosyl ligands in the 1700 and 1800 cm−1 regions for the fac and mer isomers, respectively. The ESI(+) mass spectra each display the parent ion at 647 m/z." @default.
- W1971066365 created "2016-06-24" @default.
- W1971066365 creator A5010790669 @default.
- W1971066365 creator A5013393867 @default.
- W1971066365 creator A5050979141 @default.
- W1971066365 creator A5068944189 @default.
- W1971066365 creator A5080876415 @default.
- W1971066365 creator A5091408981 @default.
- W1971066365 date "2009-08-01" @default.
- W1971066365 modified "2023-10-18" @default.
- W1971066365 title "The synthesis and X-ray structural characterization of mer and fac isomers of the technetium(I) nitrosyl complex [TcCl2(NO)(PNPpr)]" @default.
- W1971066365 cites W1970581686 @default.
- W1971066365 cites W1972267201 @default.
- W1971066365 cites W1973587493 @default.
- W1971066365 cites W1988841674 @default.
- W1971066365 cites W1992888689 @default.
- W1971066365 cites W2017070407 @default.
- W1971066365 cites W2021038178 @default.
- W1971066365 cites W2024383851 @default.
- W1971066365 cites W2050497266 @default.
- W1971066365 cites W2057071481 @default.
- W1971066365 cites W2072513800 @default.
- W1971066365 cites W2102070974 @default.
- W1971066365 cites W2145786485 @default.
- W1971066365 cites W2032443273 @default.
- W1971066365 doi "https://doi.org/10.1016/j.ica.2009.04.017" @default.
- W1971066365 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2782877" @default.
- W1971066365 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20161398" @default.
- W1971066365 hasPublicationYear "2009" @default.
- W1971066365 type Work @default.
- W1971066365 sameAs 1971066365 @default.
- W1971066365 citedByCount "8" @default.
- W1971066365 countsByYear W19710663652013 @default.
- W1971066365 countsByYear W19710663652014 @default.
- W1971066365 countsByYear W19710663652017 @default.
- W1971066365 countsByYear W19710663652022 @default.
- W1971066365 crossrefType "journal-article" @default.
- W1971066365 hasAuthorship W1971066365A5010790669 @default.
- W1971066365 hasAuthorship W1971066365A5013393867 @default.
- W1971066365 hasAuthorship W1971066365A5050979141 @default.
- W1971066365 hasAuthorship W1971066365A5068944189 @default.
- W1971066365 hasAuthorship W1971066365A5080876415 @default.
- W1971066365 hasAuthorship W1971066365A5091408981 @default.
- W1971066365 hasBestOaLocation W19710663652 @default.
- W1971066365 hasConcept C116569031 @default.
- W1971066365 hasConcept C131779359 @default.
- W1971066365 hasConcept C134121241 @default.
- W1971066365 hasConcept C155647269 @default.
- W1971066365 hasConcept C161790260 @default.
- W1971066365 hasConcept C170493617 @default.
- W1971066365 hasConcept C178790620 @default.
- W1971066365 hasConcept C185592680 @default.
- W1971066365 hasConcept C191897082 @default.
- W1971066365 hasConcept C192562407 @default.
- W1971066365 hasConcept C201194858 @default.
- W1971066365 hasConcept C2777463227 @default.
- W1971066365 hasConcept C2777716191 @default.
- W1971066365 hasConcept C55493867 @default.
- W1971066365 hasConcept C71240020 @default.
- W1971066365 hasConcept C8010536 @default.
- W1971066365 hasConceptScore W1971066365C116569031 @default.
- W1971066365 hasConceptScore W1971066365C131779359 @default.
- W1971066365 hasConceptScore W1971066365C134121241 @default.
- W1971066365 hasConceptScore W1971066365C155647269 @default.
- W1971066365 hasConceptScore W1971066365C161790260 @default.
- W1971066365 hasConceptScore W1971066365C170493617 @default.
- W1971066365 hasConceptScore W1971066365C178790620 @default.
- W1971066365 hasConceptScore W1971066365C185592680 @default.
- W1971066365 hasConceptScore W1971066365C191897082 @default.
- W1971066365 hasConceptScore W1971066365C192562407 @default.
- W1971066365 hasConceptScore W1971066365C201194858 @default.
- W1971066365 hasConceptScore W1971066365C2777463227 @default.
- W1971066365 hasConceptScore W1971066365C2777716191 @default.
- W1971066365 hasConceptScore W1971066365C55493867 @default.
- W1971066365 hasConceptScore W1971066365C71240020 @default.
- W1971066365 hasConceptScore W1971066365C8010536 @default.
- W1971066365 hasIssue "10" @default.
- W1971066365 hasLocation W19710663651 @default.
- W1971066365 hasLocation W19710663652 @default.
- W1971066365 hasLocation W19710663653 @default.
- W1971066365 hasLocation W19710663654 @default.
- W1971066365 hasOpenAccess W1971066365 @default.
- W1971066365 hasPrimaryLocation W19710663651 @default.
- W1971066365 hasRelatedWork W1990738295 @default.
- W1971066365 hasRelatedWork W2002933644 @default.
- W1971066365 hasRelatedWork W2009742489 @default.
- W1971066365 hasRelatedWork W2019454398 @default.
- W1971066365 hasRelatedWork W2028901968 @default.
- W1971066365 hasRelatedWork W2033626843 @default.
- W1971066365 hasRelatedWork W2051477743 @default.
- W1971066365 hasRelatedWork W2055902668 @default.
- W1971066365 hasRelatedWork W2057688768 @default.
- W1971066365 hasRelatedWork W2317792605 @default.
- W1971066365 hasVolume "362" @default.
- W1971066365 isParatext "false" @default.
- W1971066365 isRetracted "false" @default.
- W1971066365 magId "1971066365" @default.
- W1971066365 workType "article" @default.