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- W1971079050 abstract "Reaction of lithium salts of anilido-imine ligands bearing bulky substituentes on the nitrogen donor atoms with trans-chloro(phenyl)bis(triphenylphosphane)nickel(II) results in the formation of two rare three-coordinate nickel(I) complexes [(Ar1NCHC6H4NAr2)Ni(I)PPh3] (1: Ar1 = Ar2 = 2,6-i-Pr2C6H3; 2: Ar1 = 2,6-Me2C6H3, Ar2 = 2,6-i-Pr2C6H3). The molecular structures of complexes 1 and 2 have been confirmed by single crystal X-ray analyses. These two complexes exhibit paramagnetic properties as measured by their EPR and 1H NMR spectra. After being activated with methylaluminoxane (MAO) these complexes could polymerize norbornene to afford addition-type polynorbornene (PNB) with high molecular weight Mw (106 g mol−1), catalytic activities being high, up to 2.82 × 107 gPNB mol−1Ni h−1." @default.
- W1971079050 created "2016-06-24" @default.
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- W1971079050 date "2006-01-01" @default.
- W1971079050 modified "2023-10-17" @default.
- W1971079050 title "Synthesis, molecular structure and norbornene polymerization behavior of three-coordinate nickel(i) complexes with chelating anilido-imine ligands" @default.
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- W1971079050 doi "https://doi.org/10.1039/b516203c" @default.
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