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- W1971114691 abstract "Abstract The water soluble dicarboxylic cationic acid [(η5-C5H4COOH)2CoIII]+ (1) as its Cl− salt has been treated thermally to produce the neutral zwitterion [(η5-C5H4COOH)(η5-C5H4COO)CoIII] (2). 2 reacts with HBr in water solution to yield the bromide salt of the dicarboxylic acid [(η5-C5H4–COOH)2CoIII]Br, 1Br. Preparation of the iodide [(η5-C5H4–COOH)2CoIII]I, 1I, has been achieved by direct oxidation of [(η5-C5H4Me)2CoIII]OH with KMnO4 immediately followed by reaction with HI. The crystal structures of 1Br and 1I have been determined by single crystal X-ray diffraction. The hydrogen bonding interactions between the acid cations and between the acid cation and the halide ions have been investigated." @default.
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- W1971114691 date "2003-02-01" @default.
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- W1971114691 title "The reaction of the organometallic acid [(η5-C5H4COOH)2CoIII]+ with HBr and HI. Preparation and characterisation of [(η5-C5H4COOH)2CoIII]Br and [(η5-C5H4COOH)2CoIII]I and hydrogen bridges between cations" @default.
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- W1971114691 doi "https://doi.org/10.1016/s0022-2860(02)00508-2" @default.
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