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- W1971203036 abstract "The reaction between octacarbonyl-dicobalt and triphenylphosphine has been investigated. While other researches had obtained from this reaction a product formulated as {Co[(C6H5)3P] (CO)3}2, the present investigation showed that the actual product is an ionic compound, of formula {Co[(C6H5)3P]2(CO)3)} + [Co(CO)4]−. By exchange from this, other salts, such as chloride, iodide, nitrate, perchlorate, periodide, trichlorocobaltate (II) and diiodocuprate(I) were obtained. Another synthesis for some salts of the above cation is also described; i. e. the reaction of carbon monoxide at high pressure with compounds of the type Co[(C6H5)3P]2X2 which were unknown before this work." @default.
- W1971203036 created "2016-06-24" @default.
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- W1971203036 date "1958-01-01" @default.
- W1971203036 modified "2023-09-23" @default.
- W1971203036 title "Tricarbonylbis(triphenylphosphine)cobalt(I) salts" @default.
- W1971203036 cites W2096372371 @default.
- W1971203036 doi "https://doi.org/10.1016/0022-1902(58)80229-8" @default.
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