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- W1971237892 abstract "The crystal structure of Mg[Al(OCH3)2(CH3)2]2·C4H8O2 has been determined by single-crystal X-ray diffraction methods. Two molecules crystallize in an orthorhombic unit cell with dimensions a = 13.42±0.02, b = 10.74±0.02, c = 7.30± 0.02 Å. The space groups is Pnnm. Full matrix least-squares refinement with magnesium and aluminum atoms anisotropic, resulted in a fianl R value of R2=12.1%. The complex is an infinite polymer of Mg[Al(OCH3)2(CH3)2]2 units held together by dioxane molecules. About the magnesium atom the point symmetry appears to be 2/m, with the dioxane rings disordered about the two-fold axis. The metal atoms are bridged together by essentially sp2 hybridized oxygen atoms, which are coplanar with the methoxy methyl groups and the metal atoms." @default.
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- W1971237892 date "1968-07-01" @default.
- W1971237892 modified "2023-09-26" @default.
- W1971237892 title "Mg[Al(OCH3)2(CH3)2]2·C4H8O2. A novel coordination compound of a metal alkoxide and a donor molecule" @default.
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- W1971237892 doi "https://doi.org/10.1016/s0022-328x(00)88855-5" @default.
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