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- W1971256181 abstract "The asymmetric transfer hydrogenation of imines was performed with the use of a polymer-immobilized chiral catalyst. The chiral catalyst, prepared from crosslinked polystyrene-immobilized chiral 1,2-diamine monosulfonamide, was effective in the asymmetric transfer hydrogenation of N-benzyl imines in CH2Cl2 to give a chiral amine in high yield and good enantioselectivity. Furthermore, an amphiphilic polymeric catalyst prepared from crosslinked polystyrene containing sulfonated groups successfully catalyzed the asymmetric transfer hydrogenation of cyclic imines in water. Enantioenriched secondary amines with up to 94% ee were obtained by using a polymeric catalyst." @default.
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- W1971256181 date "2009-01-01" @default.
- W1971256181 modified "2023-09-26" @default.
- W1971256181 title "Asymmetric transfer hydrogenation of imines catalyzed by a polymer-immobilized chiral catalyst" @default.
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- W1971256181 doi "https://doi.org/10.1039/b815407b" @default.
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