FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1971268279> ?p ?o ?g. }

• W1971268279 endingPage "784" @default.
• W1971268279 startingPage "775" @default.
• W1971268279 abstract "Four chiral diphosphine ligands consisting of bis(2,5-diphenylphospholan-1-yl) groups connected by the sp2 carbon linkers 2,3-quinoxaline ((S,S)-Ph-Quinox), 2,3-pyrazine ((S,S)-Ph-Pyrazine), maleic anhydride ((S,S)-Ph-MalPhos), and 1,1‘-ferrocene ((S,S)-Ph-5-Fc) were synthesized, and their cationic [rhodium(I)(COD)] complexes were prepared. These complexes were tested in asymmetric hydrogenation of functionalized olefins. [((S,S)-Ph-Quinox)Rh(COD)]BF4 showed high activity and selectivity against itaconate and dehydroamino acid substrates. The corresponding (S,S)-Ph-Pyrazine and (S,S)-Ph-MalPhos complexes exhibited lower activities and selectivities. [((S,S)-Ph-5-Fc)Rh(COD)]BF4 showed high activity with low selectivity for these substrates, but high activity and selectivity against 2-C-substituted cinnamate salts, whereas rhodium complexes of (S,S)-Ph-Quinox and (R,R)-Ph-BPE showed low activity and selectivity against 2-C-substituted cinnamate salts." @default.
• W1971268279 created "2016-06-24" @default.
• W1971268279 creator A5008989311 @default.
• W1971268279 creator A5009962739 @default.
• W1971268279 creator A5033515028 @default.
• W1971268279 creator A5064347032 @default.
• W1971268279 creator A5071185837 @default.
• W1971268279 date "2007-10-19" @default.
• W1971268279 modified "2023-10-12" @default.
• W1971268279 title "Bis-(2,5-diphenylphospholanes) with sp² Carbon Linkers: Synthesis and Application in Asymmetric Hydrogenation" @default.
• W1971268279 cites W1991839781 @default.
• W1971268279 cites W1996998176 @default.
• W1971268279 cites W2004186832 @default.
• W1971268279 cites W2004787393 @default.
• W1971268279 cites W2005544088 @default.
• W1971268279 cites W2023516772 @default.
• W1971268279 cites W2032746273 @default.
• W1971268279 cites W2033841170 @default.
• W1971268279 cites W2053081268 @default.
• W1971268279 cites W2063324309 @default.
• W1971268279 cites W2080365266 @default.
• W1971268279 cites W2097446202 @default.
• W1971268279 cites W2114941977 @default.
• W1971268279 cites W2117771078 @default.
• W1971268279 cites W2147843116 @default.
• W1971268279 cites W2158429666 @default.
• W1971268279 cites W2949222284 @default.
• W1971268279 cites W2949298823 @default.
• W1971268279 cites W2950334603 @default.
• W1971268279 cites W2951735771 @default.
• W1971268279 cites W2953140753 @default.
• W1971268279 cites W2953306072 @default.
• W1971268279 doi "https://doi.org/10.1021/jo7014938" @default.
• W1971268279 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17949042" @default.
• W1971268279 hasPublicationYear "2007" @default.
• W1971268279 type Work @default.
• W1971268279 sameAs 1971268279 @default.
• W1971268279 citedByCount "43" @default.
• W1971268279 countsByYear W19712682792012 @default.
• W1971268279 countsByYear W19712682792013 @default.
• W1971268279 countsByYear W19712682792014 @default.
• W1971268279 countsByYear W19712682792015 @default.
• W1971268279 countsByYear W19712682792016 @default.
• W1971268279 countsByYear W19712682792017 @default.
• W1971268279 countsByYear W19712682792019 @default.
• W1971268279 countsByYear W19712682792020 @default.
• W1971268279 countsByYear W19712682792021 @default.
• W1971268279 countsByYear W19712682792023 @default.
• W1971268279 crossrefType "journal-article" @default.
• W1971268279 hasAuthorship W1971268279A5008989311 @default.
• W1971268279 hasAuthorship W1971268279A5009962739 @default.
• W1971268279 hasAuthorship W1971268279A5033515028 @default.
• W1971268279 hasAuthorship W1971268279A5064347032 @default.
• W1971268279 hasAuthorship W1971268279A5071185837 @default.
• W1971268279 hasConcept C118792377 @default.
• W1971268279 hasConcept C146686406 @default.
• W1971268279 hasConcept C147789679 @default.
• W1971268279 hasConcept C154881586 @default.
• W1971268279 hasConcept C155647269 @default.
• W1971268279 hasConcept C15920480 @default.
• W1971268279 hasConcept C161790260 @default.
• W1971268279 hasConcept C17525397 @default.
• W1971268279 hasConcept C178790620 @default.
• W1971268279 hasConcept C183882617 @default.
• W1971268279 hasConcept C185592680 @default.
• W1971268279 hasConcept C197356162 @default.
• W1971268279 hasConcept C2777237805 @default.
• W1971268279 hasConcept C2777666793 @default.
• W1971268279 hasConcept C2777765701 @default.
• W1971268279 hasConcept C2780362310 @default.
• W1971268279 hasConcept C2780872544 @default.
• W1971268279 hasConcept C521398313 @default.
• W1971268279 hasConcept C521977710 @default.
• W1971268279 hasConcept C52859227 @default.
• W1971268279 hasConceptScore W1971268279C118792377 @default.
• W1971268279 hasConceptScore W1971268279C146686406 @default.
• W1971268279 hasConceptScore W1971268279C147789679 @default.
• W1971268279 hasConceptScore W1971268279C154881586 @default.
• W1971268279 hasConceptScore W1971268279C155647269 @default.
• W1971268279 hasConceptScore W1971268279C15920480 @default.
• W1971268279 hasConceptScore W1971268279C161790260 @default.
• W1971268279 hasConceptScore W1971268279C17525397 @default.
• W1971268279 hasConceptScore W1971268279C178790620 @default.
• W1971268279 hasConceptScore W1971268279C183882617 @default.
• W1971268279 hasConceptScore W1971268279C185592680 @default.
• W1971268279 hasConceptScore W1971268279C197356162 @default.
• W1971268279 hasConceptScore W1971268279C2777237805 @default.
• W1971268279 hasConceptScore W1971268279C2777666793 @default.
• W1971268279 hasConceptScore W1971268279C2777765701 @default.
• W1971268279 hasConceptScore W1971268279C2780362310 @default.
• W1971268279 hasConceptScore W1971268279C2780872544 @default.
• W1971268279 hasConceptScore W1971268279C521398313 @default.
• W1971268279 hasConceptScore W1971268279C521977710 @default.
• W1971268279 hasConceptScore W1971268279C52859227 @default.
• W1971268279 hasIssue "3" @default.
• W1971268279 hasLocation W19712682791 @default.
• W1971268279 hasOpenAccess W1971268279 @default.
• W1971268279 hasPrimaryLocation W19712682791 @default.

• next