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- W1971291338 abstract "The crystal structure of a cubic Pmoverline 3 m perovskite-type doped lanthanum cobaltite, La 0.6 Sr 0.4 CoO 3−δ , has been studied using in situ neutron powder diffraction data measured at 1531 K. The refined occupancy 0.886 (6) of O atoms at the 3 d 1/2, 0, 0 site indicated an oxygen deficiency of δ = 0.34 (2) and an average valence of +2.7 for Co cations in La 0.6 Sr 0.4 CoO 3−δ at 1531 K. Refined anisotropic atomic displacement parameters and nuclear density mapping reveal that the oxygen ions in La 0.6 Sr 0.4 CoO 3−δ exhibit a large thermal motion perpendicular to the Co—O bond. A curved path for oxygen-ion migration between adjacent anion sites in La 0.6 Sr 0.4 CoO 3−δ is proposed, although it was not observed as a connected density in the experimental mapping." @default.
- W1971291338 created "2016-06-24" @default.
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- W1971291338 date "2007-11-10" @default.
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- W1971291338 title "Structural investigation of the cubic perovskite-type doped lanthanum cobaltite La<sub>0.6</sub>Sr<sub>0.4</sub>CoO<sub>3−δ</sub>at 1531 K: possible diffusion path of oxygen ions in an electrode material" @default.
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- W1971291338 doi "https://doi.org/10.1107/s0021889807048637" @default.
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