Matches in SemOpenAlex for { <https://semopenalex.org/work/W1971293370> ?p ?o ?g. }
Showing items 1 to 67 of
67
with 100 items per page.
- W1971293370 abstract "Diastereoselective intramolecular aldol condensations are investigated in an experimental and computational study of 1,6-diketones. Ab initio results show the importance of the acid medium and disapprove the possibility of a spontaneous cyclization, even for silylated compounds. The combination of both experimental and computational approaches brings valuable information on the mechanism and on the selectivity of the aldol reaction. It is found that the enolization of the diketone is a key step in acid-catalyzed mechanism. The cyclization step bears a very small activation energy. The dehydration of the aldols are discussed." @default.
- W1971293370 created "2016-06-24" @default.
- W1971293370 creator A5012413453 @default.
- W1971293370 creator A5017625870 @default.
- W1971293370 creator A5054681610 @default.
- W1971293370 creator A5089897437 @default.
- W1971293370 date "2000-12-26" @default.
- W1971293370 modified "2023-09-28" @default.
- W1971293370 title "ChemInform Abstract: Theoretical Study of Intramolecular Aldol Condensation of 1,6-Diketones: Trimethylsilyl Substituent Effect." @default.
- W1971293370 cites W2952090274 @default.
- W1971293370 doi "https://doi.org/10.1002/chin.200052038" @default.
- W1971293370 hasPublicationYear "2000" @default.
- W1971293370 type Work @default.
- W1971293370 sameAs 1971293370 @default.
- W1971293370 citedByCount "0" @default.
- W1971293370 crossrefType "journal-article" @default.
- W1971293370 hasAuthorship W1971293370A5012413453 @default.
- W1971293370 hasAuthorship W1971293370A5017625870 @default.
- W1971293370 hasAuthorship W1971293370A5054681610 @default.
- W1971293370 hasAuthorship W1971293370A5089897437 @default.
- W1971293370 hasConcept C147597530 @default.
- W1971293370 hasConcept C161790260 @default.
- W1971293370 hasConcept C178790620 @default.
- W1971293370 hasConcept C185592680 @default.
- W1971293370 hasConcept C18616679 @default.
- W1971293370 hasConcept C2777000832 @default.
- W1971293370 hasConcept C2778689049 @default.
- W1971293370 hasConcept C2781442258 @default.
- W1971293370 hasConcept C61156836 @default.
- W1971293370 hasConcept C75079739 @default.
- W1971293370 hasConceptScore W1971293370C147597530 @default.
- W1971293370 hasConceptScore W1971293370C161790260 @default.
- W1971293370 hasConceptScore W1971293370C178790620 @default.
- W1971293370 hasConceptScore W1971293370C185592680 @default.
- W1971293370 hasConceptScore W1971293370C18616679 @default.
- W1971293370 hasConceptScore W1971293370C2777000832 @default.
- W1971293370 hasConceptScore W1971293370C2778689049 @default.
- W1971293370 hasConceptScore W1971293370C2781442258 @default.
- W1971293370 hasConceptScore W1971293370C61156836 @default.
- W1971293370 hasConceptScore W1971293370C75079739 @default.
- W1971293370 hasLocation W19712933701 @default.
- W1971293370 hasOpenAccess W1971293370 @default.
- W1971293370 hasPrimaryLocation W19712933701 @default.
- W1971293370 hasRelatedWork W1584754773 @default.
- W1971293370 hasRelatedWork W1964115018 @default.
- W1971293370 hasRelatedWork W1976698393 @default.
- W1971293370 hasRelatedWork W1982926426 @default.
- W1971293370 hasRelatedWork W2013472791 @default.
- W1971293370 hasRelatedWork W2030783368 @default.
- W1971293370 hasRelatedWork W2040358293 @default.
- W1971293370 hasRelatedWork W2089195358 @default.
- W1971293370 hasRelatedWork W2105480157 @default.
- W1971293370 hasRelatedWork W2110498275 @default.
- W1971293370 hasRelatedWork W2113592820 @default.
- W1971293370 hasRelatedWork W2127206917 @default.
- W1971293370 hasRelatedWork W2576249258 @default.
- W1971293370 hasRelatedWork W2751759483 @default.
- W1971293370 hasRelatedWork W2949790481 @default.
- W1971293370 hasRelatedWork W2950502565 @default.
- W1971293370 hasRelatedWork W2950506192 @default.
- W1971293370 hasRelatedWork W2952090274 @default.
- W1971293370 hasRelatedWork W2952949405 @default.
- W1971293370 hasRelatedWork W2981418808 @default.
- W1971293370 isParatext "false" @default.
- W1971293370 isRetracted "false" @default.
- W1971293370 magId "1971293370" @default.
- W1971293370 workType "article" @default.