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- W1971295549 abstract "The crystal structure of the title compound has been determined from three-dimensional X-ray diffraction data. The structure is monoclinic, space group P21/c, with a = 12.873(4), b = 7.134(1), c = 19.446(7) Å, β = 111.29(3)°, V = 1663.97 Å3 and Z = 4. The structure was solved by direct methods and refined by least-squares to a final R = 0.039 (Rw = 0.039, Rg = 0.050). The complex forms polymeric chains of the type – O – Bi … Cl – Bi… extending approximately parallel to the b axis. Bismuth is in a distorted pentagonal bipyramidal coordination [Bi – Cl: 2.510(4) – 2.562(5) Å for the bridging and 2.771(3) – 2.909(5) Å for the non-bridging chlorine atoms, Bi – O: 2.424(8) – 2.986(9) Å, Bi – N: 2.654(10) Å]. The molecular cohesion within a polymeric chain is enhanced by hydrogen bonding, while the chains are held together by regular van der Waals forces." @default.
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- W1971295549 date "1990-01-01" @default.
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- W1971295549 title "Crystal structure and spectra of Trichloro-p-chlorobenzoyl-2-furaldehydohydrazono bismuth(III)" @default.
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- W1971295549 doi "https://doi.org/10.1524/zkri.1990.193.1-2.101" @default.
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