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- W1971295839 abstract "Zirconium titanate-stannate doped with V with co-dopants Al, In or Y was synthesised by solid state reaction and its structural (XRD, SEM), optical (DRS) and technological properties were determined to assess its potential use as ceramic pigment. These compounds have a srilankite-type, disordered orthorhombic structure, implying a random distribution of Zr, Ti, Sn and dopants in a single, strongly distorted octahedral site. Doping caused an increase of unit-cell dimensions, metal–oxygen distances and octahedron distortion. Optical spectra show crystal field electronic transitions of V4+ as well as intense bands in the blue-UV range due to V4+–V5+ intervalence charge transfer and/or to V–O charge transfer. The formation of oxygen vacancies is supposed to compensate the occurrence of V4+ ensuring the lattice charge neutrality. These srilankite-type oxides develop a deep and brilliant yellow shade with colourimetric parameters close to those of industrial ceramic pigments. Technological tests in several ceramic applications proved that zirconium titanate-stannate is very stable at high temperature, exhibiting an excellent performance in the 1200–1250 °C range, even better than praseodymium-doped zircon." @default.
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- W1971295839 date "2007-01-01" @default.
- W1971295839 modified "2023-09-30" @default.
- W1971295839 title "High-performance yellow ceramic pigments Zr(Ti1−x−ySnx−yVyMy)O4 (M=Al, In, Y): Crystal structure, colouring mechanism and technological properties" @default.
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- W1971295839 doi "https://doi.org/10.1016/j.materresbull.2006.05.014" @default.
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