FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1971297022> ?p ?o ?g. }

• W1971297022 endingPage "991" @default.
• W1971297022 startingPage "983" @default.
• W1971297022 abstract "Reaction of Ga(tBu)3 with the 1,3-diphenylamidine [PhN(H)C(H)NPh, H-dpam] yields monomeric (tBu)2Ga(dpam) (1). The partial hydrolysis of 1 results in the isolation of (tBu)2Ga(μ-dpam)(μ-OH)Ga(tBu)2 (2), whose structure consists of a gallium dimer in which the amidine and hydroxide ligands bridge two Ga(tBu)2 moieties. Reaction of [Me2Ga(μ-Cl)]2 with H-dpam results in the complex [H2-dpam] [Me2GaCl2] (3). The solid state structure of 3 indicates the presence of a hydrogen bonded cation-anion complex, in which the core has a twisted eight-membered ring configuration. The versatility of amidines as both chelating and bridging ligands to gallium is discussed with respect to the predominance of bridging and chelating modes of coordination of carboxylates and triazenides, respectively. Reaction of 2-(methylamino)pyridine (H-map) with Ga(tBu)3 allows for the isolation of (tBu)2Ga(map) (4). In contrast, reaction with [(tBu)2Ga(μ-Cl)]2 and [Me2Ga(μ-Cl)]2 yields the Lewis acid base adducts, (tBu)2GaCl(H-map) (5) and Me2GaCl(H-map) (6), respectively. Reaction of compound 6 with nPrNH2 does not result in the deprotonation of the H-map ligand, but ligand metathesis and the formation of (tBu)2GaCl(NH2nPr) (7). The structures of 2, 3, 6, and 7 have been determined by X-ray crystallography." @default.
• W1971297022 created "2016-06-24" @default.
• W1971297022 creator A5000845740 @default.
• W1971297022 creator A5018031382 @default.
• W1971297022 creator A5027916962 @default.
• W1971297022 creator A5058660064 @default.
• W1971297022 date "1998-03-01" @default.
• W1971297022 modified "2023-10-18" @default.
• W1971297022 title "1,3-diphenylamidine and methylaminopyridine compounds of gallium" @default.
• W1971297022 cites W1966810624 @default.
• W1971297022 cites W1975650712 @default.
• W1971297022 cites W1984053247 @default.
• W1971297022 cites W1985826463 @default.
• W1971297022 cites W1987734294 @default.
• W1971297022 cites W1990148488 @default.
• W1971297022 cites W1996371859 @default.
• W1971297022 cites W2007730532 @default.
• W1971297022 cites W2009296705 @default.
• W1971297022 cites W2030061928 @default.
• W1971297022 cites W2034390035 @default.
• W1971297022 cites W2038752269 @default.
• W1971297022 cites W2043430559 @default.
• W1971297022 cites W2048967314 @default.
• W1971297022 cites W2055749414 @default.
• W1971297022 cites W2074136849 @default.
• W1971297022 cites W2076726825 @default.
• W1971297022 cites W2076768121 @default.
• W1971297022 cites W2089459008 @default.
• W1971297022 cites W2112448974 @default.
• W1971297022 cites W2156257115 @default.
• W1971297022 cites W2324082436 @default.
• W1971297022 cites W2950560312 @default.
• W1971297022 cites W960968182 @default.
• W1971297022 doi "https://doi.org/10.1016/s0277-5387(97)00205-2" @default.
• W1971297022 hasPublicationYear "1998" @default.
• W1971297022 type Work @default.
• W1971297022 sameAs 1971297022 @default.
• W1971297022 citedByCount "22" @default.
• W1971297022 countsByYear W19712970222012 @default.
• W1971297022 countsByYear W19712970222014 @default.
• W1971297022 countsByYear W19712970222016 @default.
• W1971297022 countsByYear W19712970222023 @default.
• W1971297022 crossrefType "journal-article" @default.
• W1971297022 hasAuthorship W1971297022A5000845740 @default.
• W1971297022 hasAuthorship W1971297022A5018031382 @default.
• W1971297022 hasAuthorship W1971297022A5027916962 @default.
• W1971297022 hasAuthorship W1971297022A5058660064 @default.
• W1971297022 hasConcept C115624301 @default.
• W1971297022 hasConcept C116569031 @default.
• W1971297022 hasConcept C118629725 @default.
• W1971297022 hasConcept C145148216 @default.
• W1971297022 hasConcept C155647269 @default.
• W1971297022 hasConcept C170493617 @default.
• W1971297022 hasConcept C178516000 @default.
• W1971297022 hasConcept C178790620 @default.
• W1971297022 hasConcept C179104552 @default.
• W1971297022 hasConcept C185592680 @default.
• W1971297022 hasConcept C197404232 @default.
• W1971297022 hasConcept C2778622868 @default.
• W1971297022 hasConcept C2779485729 @default.
• W1971297022 hasConcept C2779546866 @default.
• W1971297022 hasConcept C55493867 @default.
• W1971297022 hasConcept C71240020 @default.
• W1971297022 hasConcept C8010536 @default.
• W1971297022 hasConceptScore W1971297022C115624301 @default.
• W1971297022 hasConceptScore W1971297022C116569031 @default.
• W1971297022 hasConceptScore W1971297022C118629725 @default.
• W1971297022 hasConceptScore W1971297022C145148216 @default.
• W1971297022 hasConceptScore W1971297022C155647269 @default.
• W1971297022 hasConceptScore W1971297022C170493617 @default.
• W1971297022 hasConceptScore W1971297022C178516000 @default.
• W1971297022 hasConceptScore W1971297022C178790620 @default.
• W1971297022 hasConceptScore W1971297022C179104552 @default.
• W1971297022 hasConceptScore W1971297022C185592680 @default.
• W1971297022 hasConceptScore W1971297022C197404232 @default.
• W1971297022 hasConceptScore W1971297022C2778622868 @default.
• W1971297022 hasConceptScore W1971297022C2779485729 @default.
• W1971297022 hasConceptScore W1971297022C2779546866 @default.
• W1971297022 hasConceptScore W1971297022C55493867 @default.
• W1971297022 hasConceptScore W1971297022C71240020 @default.
• W1971297022 hasConceptScore W1971297022C8010536 @default.
• W1971297022 hasIssue "5-6" @default.
• W1971297022 hasLocation W19712970221 @default.
• W1971297022 hasOpenAccess W1971297022 @default.
• W1971297022 hasPrimaryLocation W19712970221 @default.
• W1971297022 hasRelatedWork W1963901212 @default.
• W1971297022 hasRelatedWork W1972063043 @default.
• W1971297022 hasRelatedWork W2016500127 @default.
• W1971297022 hasRelatedWork W2020299399 @default.
• W1971297022 hasRelatedWork W2044207546 @default.
• W1971297022 hasRelatedWork W2094386971 @default.
• W1971297022 hasRelatedWork W2135244721 @default.
• W1971297022 hasRelatedWork W2313979199 @default.
• W1971297022 hasRelatedWork W2950577435 @default.
• W1971297022 hasRelatedWork W3004823135 @default.
• W1971297022 hasVolume "17" @default.
• W1971297022 isParatext "false" @default.
• W1971297022 isRetracted "false" @default.

• next