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• W1971297072 abstract "Two new solubility-limiting phases relevant to nuclear waste disposal are reported, namely CeSiO 4 and Ca 2 Ce 8 ( SiO 4 ) O 2 , produced by hydrothermal synthesis at 180 ° C . X-ray diffraction data are presented for both compounds. Rietveld refinement was performed for each of these phases. CeSiO 4 was confirmed to be a zircon structure type, with space group I 4 1 / amd , unit cell type = bold > a bold=6.9564(3) , type = bold > c bold=6.1953(4) Å . Bond lengths for SiO 4 are in excellent agreement with published values; Ce 4+ is coordinated to eight oxygen atoms with four regular and four short bonds. Ca 2 Ce 8 ( SiO 4 ) O 2 was shown to have an apatite structure, with space group P 6 3 / m and unit cell type = bold > a bold=9.4343(3) , type = bold > c bold=6.8885(4) Å . The unit cell and bond lengths were found to be slightly smaller than would be expected from other lanthanide-containing analogs; possible reasons for this are discussed." @default.
• W1971297072 created "2016-06-24" @default.
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• W1971297072 date "2000-12-01" @default.
• W1971297072 modified "2023-10-11" @default.
• W1971297072 title "The crystal structures of <i>CeSiO</i>₄ and <i>Ca</i>₂<i>Ce</i>₈(<i>SiO</i>₄)₆<i>O</i>₂" @default.
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• W1971297072 doi "https://doi.org/10.1017/s0885715600011143" @default.
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