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- W1971305412 abstract "Abstract The reaction of MgBu 2 with 1 equiv. of four‐coordinating ( R )‐ or rac ‐ N , N ‐bis(3,5‐di‐ tert ‐butylbenzyl‐2‐hydroxy)tetrahydrofurfurylamine ( R / rac ‐bpthfa‐H 2 ) gave dinuclear homoleptic [Mg(μ‐ R / rac ‐bpthfa)] 2 ( R / rac ‐ 2c ) as white powders in54–67 % yields. Analogous reactions of MgBu 2 with 2 equiv. of two‐coordinating N ‐(3,5‐di‐ tert ‐butylbenzyl‐2‐hydroxy)‐ N ‐methylcyclohexanamine (tbpca‐H; 1e ‐H) and ( S )‐ N ‐(3,5‐di‐ tert ‐butylbenzyl‐2‐hydroxy)‐ N ,α‐dimethylbenzylamine( S ‐tbpmpa‐H; S ‐ 1f ‐H) gave white crystals of homoleptic mononuclear compounds of general formula [Mg(L) 2 ] ( 2e and S ‐ 2f ) in 87–89 % yields. The resulting aminophenolates were characterized by spectroscopic methods and, in the case of R ‐ 2c and S ‐ 2f , by X‐ray crystallography. The new complexes R / rac ‐ 2c , 2e , and S ‐ 2f , as well as the previously described homo‐ and heteroleptic tetranuclear [Mg(ddbfo) 2 ] 4 ( 2a ), [Mg(thffo) 2 ] 4 ( 2b ), [Mg 4 (μ 3 ‐OMe) 2 (μ,η 2 ‐ddbfo) 2 (μ,η 1 ‐ddbfo) 2 (η 1 ‐ddbfo) 2 (MeOH) 5 ] · CH 3 OH · thf ( 3a· CH 3 OH · thf) and [Mg 4 (μ 3 ,η 2 ‐thffo) 2 (μ,η 2 ‐thffo) 2 (Ph 3 SiO) 2 ] ( 4b ), were tested in the polymerization of lactide to reveal good activity only in the case of mononuclear four‐coordinate species grafted with an external donor, benzyl alcohol." @default.
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- W1971305412 date "2010-07-07" @default.
- W1971305412 modified "2023-09-23" @default.
- W1971305412 title "Synthesis, Characterization, and Catalytic Studies of (Aryloxido)magnesium Complexes" @default.
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- W1971305412 doi "https://doi.org/10.1002/ejic.200901207" @default.
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