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- W1971369908 abstract "Abstract Cis - trans isomerism reactions of cis -Pt(MNZ) 2 X 2 complexes, where MNZ is metronidazole [1-(2′-hydroxyethyl)-2-methyl-5-nitroimidazole] and X = Cl, Br or I, occur in both the solid-state and in solution, and were studied by differential scanning calorimetry and multinuclear NMR spectroscopy. For the solid-state process, enthalpies of isomerization ranged from −21 to −49 kJ mol −1 . First order rate constants were determined from 195 Pt NMR measurements in solution; consideration of the effects of added halides and free ligand suggests that the reaction mechanism involves associative processes." @default.
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- W1971369908 date "1991-01-01" @default.
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- W1971369908 title "Studies of the cis-trans isomerism of some square-planar platinum(II) nitroimidazole complexes" @default.
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- W1971369908 doi "https://doi.org/10.1016/s0277-5387(00)81281-4" @default.
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