FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1971386814> ?p ?o ?g. }

• W1971386814 endingPage "1744" @default.
• W1971386814 startingPage "1742" @default.
• W1971386814 abstract "Reaction of the trivalent uranium complex U(O-2,6-tBu2C6H3)3(THF) (4) with copper(I) iodide affords the corresponding uranium(IV) mixed iodide–aryloxide complex (I)U(O-2,6-tBu2C6H3)3(THF) (5). The oxidative functionalization protocol can also be extended to the synthesis of (Cl)U[N(SiMe3)2]3 (7) from the reaction of the tris(amide) uranium(III) complex U[N(SiMe3)2]3 (6) with copper(I) chloride. These represent the first examples of Cu-based oxidative functionalization of simple trivalent uranium coordination complexes supported by non-metallocene ligand frameworks. With several advantages over existing oxidation methods for uranium tris(aryloxide) and tris(amide) complexes, this Cu-based procedure promises to be a useful and versatile synthetic protocol for uranium chemistry. The X-ray crystal structure of (I)U(O-2,6-tBu2C6H3)3(THF) (5) is also reported and represents a rare example of a structurally characterized 5-coordinate uranium aryloxide complex. In the solid-state, complex 5 adopts a distorted square pyramidal geometry about the uranium atom, with the iodide ligand occupying the axial position and the THF and three 2,6-di-tert-butylphenoxide ligands occupying the sites of the square pyramid base." @default.
• W1971386814 created "2016-06-24" @default.
• W1971386814 creator A5033721117 @default.
• W1971386814 creator A5055551254 @default.
• W1971386814 creator A5067137772 @default.
• W1971386814 creator A5086077605 @default.
• W1971386814 date "2011-11-01" @default.
• W1971386814 modified "2023-09-27" @default.
• W1971386814 title "Straightforward and efficient oxidation of tris(aryloxide) and tris(amide) uranium(III) complexes using copper(I) halide reagents" @default.
• W1971386814 cites W1963749305 @default.
• W1971386814 cites W1965208691 @default.
• W1971386814 cites W1965572555 @default.
• W1971386814 cites W1965654005 @default.
• W1971386814 cites W1972558430 @default.
• W1971386814 cites W1976263143 @default.
• W1971386814 cites W1989250325 @default.
• W1971386814 cites W1989852103 @default.
• W1971386814 cites W1993412466 @default.
• W1971386814 cites W2008698233 @default.
• W1971386814 cites W2009378944 @default.
• W1971386814 cites W2012209451 @default.
• W1971386814 cites W2021378039 @default.
• W1971386814 cites W2021963685 @default.
• W1971386814 cites W2022231330 @default.
• W1971386814 cites W2027711190 @default.
• W1971386814 cites W2030057788 @default.
• W1971386814 cites W2040573684 @default.
• W1971386814 cites W2063074480 @default.
• W1971386814 cites W2085055453 @default.
• W1971386814 cites W2106815903 @default.
• W1971386814 cites W2160446852 @default.
• W1971386814 cites W2162656189 @default.
• W1971386814 cites W2168915189 @default.
• W1971386814 cites W2283220043 @default.
• W1971386814 cites W92069352 @default.
• W1971386814 doi "https://doi.org/10.1016/j.inoche.2011.07.019" @default.
• W1971386814 hasPublicationYear "2011" @default.
• W1971386814 type Work @default.
• W1971386814 sameAs 1971386814 @default.
• W1971386814 citedByCount "14" @default.
• W1971386814 countsByYear W19713868142012 @default.
• W1971386814 countsByYear W19713868142014 @default.
• W1971386814 countsByYear W19713868142015 @default.
• W1971386814 countsByYear W19713868142016 @default.
• W1971386814 countsByYear W19713868142017 @default.
• W1971386814 countsByYear W19713868142019 @default.
• W1971386814 countsByYear W19713868142020 @default.
• W1971386814 crossrefType "journal-article" @default.
• W1971386814 hasAuthorship W1971386814A5033721117 @default.
• W1971386814 hasAuthorship W1971386814A5055551254 @default.
• W1971386814 hasAuthorship W1971386814A5067137772 @default.
• W1971386814 hasAuthorship W1971386814A5086077605 @default.
• W1971386814 hasConcept C115624301 @default.
• W1971386814 hasConcept C116569031 @default.
• W1971386814 hasConcept C161790260 @default.
• W1971386814 hasConcept C170493617 @default.
• W1971386814 hasConcept C171560689 @default.
• W1971386814 hasConcept C178790620 @default.
• W1971386814 hasConcept C179104552 @default.
• W1971386814 hasConcept C185592680 @default.
• W1971386814 hasConcept C188027245 @default.
• W1971386814 hasConcept C191897082 @default.
• W1971386814 hasConcept C192562407 @default.
• W1971386814 hasConcept C2778439535 @default.
• W1971386814 hasConcept C2778591166 @default.
• W1971386814 hasConcept C2778870691 @default.
• W1971386814 hasConcept C2781014771 @default.
• W1971386814 hasConcept C40875361 @default.
• W1971386814 hasConcept C544778455 @default.
• W1971386814 hasConcept C55493867 @default.
• W1971386814 hasConcept C555451288 @default.
• W1971386814 hasConcept C8010536 @default.
• W1971386814 hasConcept C94882840 @default.
• W1971386814 hasConceptScore W1971386814C115624301 @default.
• W1971386814 hasConceptScore W1971386814C116569031 @default.
• W1971386814 hasConceptScore W1971386814C161790260 @default.
• W1971386814 hasConceptScore W1971386814C170493617 @default.
• W1971386814 hasConceptScore W1971386814C171560689 @default.
• W1971386814 hasConceptScore W1971386814C178790620 @default.
• W1971386814 hasConceptScore W1971386814C179104552 @default.
• W1971386814 hasConceptScore W1971386814C185592680 @default.
• W1971386814 hasConceptScore W1971386814C188027245 @default.
• W1971386814 hasConceptScore W1971386814C191897082 @default.
• W1971386814 hasConceptScore W1971386814C192562407 @default.
• W1971386814 hasConceptScore W1971386814C2778439535 @default.
• W1971386814 hasConceptScore W1971386814C2778591166 @default.
• W1971386814 hasConceptScore W1971386814C2778870691 @default.
• W1971386814 hasConceptScore W1971386814C2781014771 @default.
• W1971386814 hasConceptScore W1971386814C40875361 @default.
• W1971386814 hasConceptScore W1971386814C544778455 @default.
• W1971386814 hasConceptScore W1971386814C55493867 @default.
• W1971386814 hasConceptScore W1971386814C555451288 @default.
• W1971386814 hasConceptScore W1971386814C8010536 @default.
• W1971386814 hasConceptScore W1971386814C94882840 @default.
• W1971386814 hasIssue "11" @default.
• W1971386814 hasLocation W19713868141 @default.
• W1971386814 hasOpenAccess W1971386814 @default.
• W1971386814 hasPrimaryLocation W19713868141 @default.

• next