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• W1971387462 abstract "Abstract It is assumed that the relationship between the numbers of adsorption sites and adsorbRtes might be associated with the conditions under which the Freundlich equation could be applied to adsorption phenomena as an isotherm. We constracted several stochastic models based on the numbers of adsorption sites and adsorbRtes, and simulated the models using a computer. By using the relationship between the Freundlich isotherm coefficients, log K F and 1 / n, we examined the conditions under which the Freundlich equation could be applied to adsorption phenomena. In the one..imensional model considered to repeat adsorp tion and desorption phenomena until equilibrium was reached, the relationship between the Freundlich isotherm coefficients was fulfilled when the number of desorbed adsorbRtes was fixed for the adsorption sites. In the case of practical experiments, the number of adsorption sites was much larger than the number of adsorbRtes in the initial solution. Therefore, it was assumed that the difference in the number of adsorption sites did not reflect the results, and emphasis was placed on the difference in the ratio of desorbed adsorbates in practical experiments" @default.
• W1971387462 created "2016-06-24" @default.
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• W1971387462 date "2004-02-01" @default.
• W1971387462 modified "2023-09-26" @default.
• W1971387462 title "Identification of adsorption conditions fulfilling the correlation between freundlich isotherm coeficients, log<i>K</i>_Fand 1/<i>n</i>by computer simulation" @default.
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• W1971387462 doi "https://doi.org/10.1080/00380768.2004.10408466" @default.
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