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- W1971399998 abstract "Using titanium columns of 10 cm length and glass columns of different lengths, the vertical exponential distribution of the concentration of aqueous 1–1 electrolytes in each column has been ascertained at the steady state of convective thermal diffusion. The value of(a4⁄L) In q is found to be characteristic of individual solutes, and possibly proportional to the thermal diffusion coefficients, where q is the quotient of the steady concentration of a solute at the bottom of column to that at the top, L is the effective column length, and a is the working column space. This fact has been also shown by jointed glass columns with and without top vessel, capable of multistep sampling from the top to the bottom through intermediate jointed parts along columns. The rate constants in processes to the steady state have been examined to be proportional to the square of temperature difference applied, and to decrease with increasing L. Although the enhancement of downward enrichment of solutes has been observed by attaching a large top vessel to the column top, the rate constants decrease inevitably and significantly thereby." @default.
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- W1971399998 date "1984-02-01" @default.
- W1971399998 modified "2023-09-30" @default.
- W1971399998 title "Exponential Distribution of Aqueous 1–1 Electrolytes Due to Convective Thermal Diffusion in Vertical Columns" @default.
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- W1971399998 doi "https://doi.org/10.1246/bcsj.57.349" @default.
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