Matches in SemOpenAlex for { <https://semopenalex.org/work/W1971407017> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W1971407017 endingPage "2872" @default.
- W1971407017 startingPage "2865" @default.
- W1971407017 abstract "An alkali-soluble random copolymer (ASR), poly(styrene/α-methylstyrene/acrylic acid), was used as a polymeric emulsifier in the emulsion polymerization of styrene. The calorimetric technique was applied to study the kinetics of emulsion polymerization of styrene using ASR and a conventional ionic emulsifier, sodium dodecyl benzenesulfonate (SDBS). ASR could form aggregates like micelles, and the solubilization ability of the aggregates was dependent on the neutralization degree of ASR. The rate of polymerization in the ASR system was lower than that in the SDBS system. This result can be explained by the creation of a hairy ASR layer around the particle surface, which decreases the diffusion rate of free radicals through this region. Although a decrease in particle size was observed, the rate of polymerization decreased with increasing ASR concentration. The higher the concentration of ASR is, the thicker and denser ASR layer may be, and the more difficult it would therefore be for radicals to reach the particle through this layer of ASR. The rate of polymerization decreased with increasing the neutralization degree of ASR. The aggregates with high neutralization of ASR are less efficient in solubilizing the monomer and capturing initiator radicals than that of the lower neutralization degree, which leads to decrease in rate of polymerization. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 2865–2872, 1998" @default.
- W1971407017 created "2016-06-24" @default.
- W1971407017 creator A5022943650 @default.
- W1971407017 creator A5076922511 @default.
- W1971407017 date "1998-11-30" @default.
- W1971407017 modified "2023-10-14" @default.
- W1971407017 title "Emulsion polymerization of styrene using an alkali-soluble random copolymer as polymeric emulsifier" @default.
- W1971407017 doi "https://doi.org/10.1002/(sici)1099-0518(19981130)36:16<2865::aid-pola4>3.0.co;2-7" @default.
- W1971407017 hasPublicationYear "1998" @default.
- W1971407017 type Work @default.
- W1971407017 sameAs 1971407017 @default.
- W1971407017 citedByCount "20" @default.
- W1971407017 countsByYear W19714070172016 @default.
- W1971407017 countsByYear W19714070172017 @default.
- W1971407017 countsByYear W19714070172018 @default.
- W1971407017 countsByYear W19714070172019 @default.
- W1971407017 countsByYear W19714070172022 @default.
- W1971407017 countsByYear W19714070172023 @default.
- W1971407017 crossrefType "journal-article" @default.
- W1971407017 hasAuthorship W1971407017A5022943650 @default.
- W1971407017 hasAuthorship W1971407017A5076922511 @default.
- W1971407017 hasConcept C111998727 @default.
- W1971407017 hasConcept C127413603 @default.
- W1971407017 hasConcept C147789679 @default.
- W1971407017 hasConcept C15920480 @default.
- W1971407017 hasConcept C166940927 @default.
- W1971407017 hasConcept C178790620 @default.
- W1971407017 hasConcept C185592680 @default.
- W1971407017 hasConcept C187530423 @default.
- W1971407017 hasConcept C188027245 @default.
- W1971407017 hasConcept C191516044 @default.
- W1971407017 hasConcept C192562407 @default.
- W1971407017 hasConcept C199002037 @default.
- W1971407017 hasConcept C2777566558 @default.
- W1971407017 hasConcept C2778123984 @default.
- W1971407017 hasConcept C2780503075 @default.
- W1971407017 hasConcept C42360764 @default.
- W1971407017 hasConcept C44228677 @default.
- W1971407017 hasConcept C521977710 @default.
- W1971407017 hasConceptScore W1971407017C111998727 @default.
- W1971407017 hasConceptScore W1971407017C127413603 @default.
- W1971407017 hasConceptScore W1971407017C147789679 @default.
- W1971407017 hasConceptScore W1971407017C15920480 @default.
- W1971407017 hasConceptScore W1971407017C166940927 @default.
- W1971407017 hasConceptScore W1971407017C178790620 @default.
- W1971407017 hasConceptScore W1971407017C185592680 @default.
- W1971407017 hasConceptScore W1971407017C187530423 @default.
- W1971407017 hasConceptScore W1971407017C188027245 @default.
- W1971407017 hasConceptScore W1971407017C191516044 @default.
- W1971407017 hasConceptScore W1971407017C192562407 @default.
- W1971407017 hasConceptScore W1971407017C199002037 @default.
- W1971407017 hasConceptScore W1971407017C2777566558 @default.
- W1971407017 hasConceptScore W1971407017C2778123984 @default.
- W1971407017 hasConceptScore W1971407017C2780503075 @default.
- W1971407017 hasConceptScore W1971407017C42360764 @default.
- W1971407017 hasConceptScore W1971407017C44228677 @default.
- W1971407017 hasConceptScore W1971407017C521977710 @default.
- W1971407017 hasIssue "16" @default.
- W1971407017 hasLocation W19714070171 @default.
- W1971407017 hasOpenAccess W1971407017 @default.
- W1971407017 hasPrimaryLocation W19714070171 @default.
- W1971407017 hasRelatedWork W2027409858 @default.
- W1971407017 hasRelatedWork W2087936777 @default.
- W1971407017 hasRelatedWork W2151056968 @default.
- W1971407017 hasRelatedWork W2355494537 @default.
- W1971407017 hasRelatedWork W2390712972 @default.
- W1971407017 hasRelatedWork W2392768995 @default.
- W1971407017 hasRelatedWork W2394514596 @default.
- W1971407017 hasRelatedWork W2404725311 @default.
- W1971407017 hasRelatedWork W2416200675 @default.
- W1971407017 hasRelatedWork W2490221556 @default.
- W1971407017 hasVolume "36" @default.
- W1971407017 isParatext "false" @default.
- W1971407017 isRetracted "false" @default.
- W1971407017 magId "1971407017" @default.
- W1971407017 workType "article" @default.