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- W1971427227 abstract "The infrared spectrum of difluoro disulphane, FSSF, and the Raman spectra of difluoro disulphane and thio-thionyl fluoride, SSF2 have been recorded. Six fundamentals of FSSP (point group C2) were observed and have been assigned as follows: Species A: ν1(SF) 717.0 ± 0.5 cm−1, ν2(SS) 614.6 ± 0.4 cm− ν3(FSS) 319.8 ± 0.3 cm−1, ν4(FSS) 182.5 ± 1.5 cm−1 Species B: ν5(SF) 680.8 ± 0.3 cm−1, ν6(FSS) 301 ± 2 cm−1 A normal co-ordinate vibrational analysis was performed using a modified Urey-Bradley potential function. Calculated values for the S—F and S—S force constants are 3.2 and 3.7 mdynA respectively; the latter constant is surprisingly small for the S—S bond length of 1.888 ± 0.01 Å in FSSF. The fundamentals in our reported infrared spectrum of SSF2 (point group C3) have been re-assigned on the basis of the present Raman data: Species A': ν1 760.5 ± 0.2 cm−1, ν2 718.5 ± 0.2 cm−1 ν3 411.2 ± 0.4 cm−1, ν4 330 ±1.5 cm−1 Species A″: ν5 692.3 ± 0.8 cm−1, ν6 274 ± 1.5 cm−1 Thermodynamic functions have been calculated for FSSF and SSF2 using the harmonic oscillator ideal gas approximation." @default.
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- W1971427227 date "1970-07-01" @default.
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- W1971427227 title "Vibrational spectra of thio-thionyl fluoride and difluoro disulphane" @default.
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- W1971427227 doi "https://doi.org/10.1016/0584-8539(70)80199-4" @default.
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