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• W1971437003 abstract "The polycarbynes are polymeric precursors that can be used in the synthesis of both diamond films and powders. They are soluble in common organic solvents; therefore, they can be coated on any surface in various thicknesses and then converted to diamond via sintering. Polycarbynes can be synthesized in a simple undivided electrochemical cell so their synthesis are both cheap and easy. Here, we report the electrochemical synthesis of poly(methylcarbyne). The poly(methylcarbyne) was characterized using UV/visible spectroscopy, Gel Permeation Chromatography and ATR FTIR, 1H NMR, 13C NMR spectroscopies. The polymer was converted to diamond via sintering and characterized by Optical microscopy and Raman and X-ray spectroscopies. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012" @default.
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• W1971437003 date "2011-11-22" @default.
• W1971437003 modified "2023-10-16" @default.
• W1971437003 title "The electrochemical synthesis of poly(methylcarbyne) for diamond film coatings" @default.
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• W1971437003 doi "https://doi.org/10.1002/app.34805" @default.
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