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• W1971478412 startingPage "11259" @default.
• W1971478412 abstract "A theory is presented that describes the dynamical effects in the neutralization rate of a physisorbed ion due to the electron tunneling from the surface band. The theory is applied to the stimulated desorption of particles physisorbed at a metal surface. It is found that the dynamical effects crucially influence a position dependence of the neutralization rate in the crossover region in which the valence level of the particle intersects either edge of a filled electronic band in the metal. The neutralization rate does not follow the density of states of the band near its edge, and significant deviations from the golden-rule formula are predicted. How the neutralization rate approaches the values predicted by the golden rule with an increase of the particle mass and/or a decrease of the distance between the region of the primary excitation (triggering the desorption process) and the onset of the crossover is also made clear." @default.
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• W1971478412 date "1989-06-01" @default.
• W1971478412 modified "2023-10-02" @default.
• W1971478412 title "Ion neutralization in stimulated desorption" @default.
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• W1971478412 doi "https://doi.org/10.1103/physrevb.39.11259" @default.
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