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• W1971482816 abstract "Abstract Excess molar enthalpies Hm E at 298.15 K and atmospheric pressure for the five binary mixtures of 2-heptanone with n-propanol, n-pentanol, n-hexanol, n-heptanol and n-octanol have been obtained over the whole mole fraction range using a Calvet microcalorimeter. In addition, a vibrating-tube digital densimeter was used to determine the excess molar volumes Vm E at the same temperature and pressure for the four different binary mixtures of 2-heptanone with n-propanol, n-hexanol, n-heptanol and n-octanol. The results show that all the systems are endothermic; Hm E values increase with the number of carbons of the alkanol. The excess molar volumes are sigmoid for n-propanol and increasingly positive for the large alkanols. Two methods of correlating the results with a variable-degree polynomial are examined. The experimental results are compared with the predictions of Prigogine-Flory-Patterson theory. Key Words: Excess molar enthalpies and molar volumesCalvet microcalorimeterPrigogine-Flory-Patterson theory" @default.
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• W1971482816 date "1994-05-01" @default.
• W1971482816 modified "2023-10-09" @default.
• W1971482816 title "Thermodynamics of the Binary Mixtures of 2-Heptanone with an<i>n</i>-Alkanol at 298.15 K" @default.
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• W1971482816 doi "https://doi.org/10.1080/00319109408029520" @default.
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