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• W1971485345 startingPage "1137" @default.
• W1971485345 abstract "The nickel, copper, and silver metal carbonyl chloride molecules have been prepared and isolated in solid argon by cocondensation of the species generated from 1064 nm laser ablation of metal chlorides with carbon monoxide in excess argon at 11 K. On the basis of isotopic substitution experiments and density functional theory frequency calculations, infrared absorptions at 2118.7, 2156.8, and 2184.0 cm-1 are assigned to the C−O stretching vibrations of the Ni(CO)Cl, Cu(CO)Cl, and Ag(CO)Cl molecules. Density functional calculations predicted that the M(CO)Cl (M = Ni, Cu, Ag) molecules are linear; the binding energies with respect to MCl + CO were estimated to be 37.7, 34.2, and 17.8 kcal/mol, respectively. In addition, evidence is also presented for the M(CO)Cl2, M(CO)2Cl, and M(CO)2Cl2 (M = Ni, Cu) molecules." @default.
• W1971485345 created "2016-06-24" @default.
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• W1971485345 date "2001-02-16" @default.
• W1971485345 modified "2023-10-11" @default.
• W1971485345 title "Matrix Isolation FTIR Spectroscopic and Density Functional Theoretical Studies of the Nickel, Copper, and Silver Carbonyl Chlorides" @default.
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• W1971485345 doi "https://doi.org/10.1021/om000911h" @default.
• W1971485345 hasPublicationYear "2001" @default.
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