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- W1971495625 abstract "Ionic [(CpFeCO)2(μ-CO)(μ-CCHCH−)]+ fragments were used as electron acceptors in combination with para-substituted stilbenyl donors to form push−pull chromophores. These μ-vinylcarbyne salts were prepared by two complementary procedures: (a) the direct condensation of the μ-ethylidyne complex [(CpFeCO)2(μ-CO)(μ-CCH3)][BF4] with various stilbenyl aldehydes and (b) the preparation and reaction of the neutral aldehyde [(CpFeCO)2(μ-CO)(μ-CCHCH2C6H4CHO)] with Wittig reagents followed by hydride abstraction using [Ph3C][BF4]. While the series did exhibit high nonlinear activity (measured by hyper-Rayleigh scattering techniques), fluorescence checks revealed emission bands in the proximity of the second harmonic signal due to two-photon absorption." @default.
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- W1971495625 date "2000-07-27" @default.
- W1971495625 modified "2023-09-27" @default.
- W1971495625 title "Linear and Nonlinear Optical Properties of Diiron μ-Vinylcarbyne Acceptor and Stilbenyl Donor Based Chromophores" @default.
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- W1971495625 doi "https://doi.org/10.1021/om000112z" @default.
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