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- W1971501793 abstract "The synthesis of MeLeu and MeLeu-D-Leu alkene dipeptide isosteres are described. Isosteres with an E-alkene bond were synthesized stereoselectively by employing the [2, 3] Wittig rearrangement to control double bond geometry and C-2 configuration. Z-alkene isosters were obtained as an easily separable mixture of diastereomers via alkylation of a Z-alkene MeLeu-Gly isostere that was obtained using a Z-selective Wittig reaction as the key step. All isosteres are isolated with high stereochemical purity." @default.
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- W1971501793 date "1993-08-01" @default.
- W1971501793 modified "2023-10-12" @default.
- W1971501793 title "Synthesis of E- and Z-alkene dipeptide isosteres" @default.
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- W1971501793 doi "https://doi.org/10.1016/s0040-4039(00)73956-6" @default.
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