FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1971514240> ?p ?o ?g. }

• W1971514240 endingPage "4796" @default.
• W1971514240 startingPage "4791" @default.
• W1971514240 abstract "Nanoparticles of certain materials can respond structurally to changes in their surface environments. We have previously shown that methanol, water adsorption, and aggregation−disaggregation can change the structure of 3 nm diameter zinc sulfide (ZnS). However, in prior observations of water-driven structure change, aggregation also may have taken place. Therefore, we investigated the structural consequences of water adsorption alone on anhydrous nanoparticles that were dried to minimize changes in aggregation. Using simultaneously collected small- and wide-angle X-ray scattering (SAXS and WAXS) data, we showed that water vapor adsorption alone drives a structural transformation in ZnS nanoparticles in the temperature range of 22−40 °C. The transition kinetics is strongly temperature dependent, with an activation energy of 55 ± 10 kJ/mol, consistent with atom displacement rather than bond breaking. At 50 °C, aggregate restructuring occurred, increasing the transition kinetics beyond the rate expected for water adsorption alone. The observation of isosbestic points in the WAXS data suggests that the particles do not transform continuously between the initial and the final structural state but rather undergo an abrupt change from a less ordered to a more ordered state." @default.
• W1971514240 created "2016-06-24" @default.
• W1971514240 creator A5008370598 @default.
• W1971514240 creator A5019639436 @default.
• W1971514240 creator A5039292363 @default.
• W1971514240 creator A5045720453 @default.
• W1971514240 date "2008-03-11" @default.
• W1971514240 modified "2023-09-26" @default.
• W1971514240 title "Kinetics of Water Adsorption-Driven Structural Transformation of ZnS Nanoparticles" @default.
• W1971514240 cites W1969017627 @default.
• W1971514240 cites W1987305625 @default.
• W1971514240 cites W1989347273 @default.
• W1971514240 cites W1991357054 @default.
• W1971514240 cites W1993640088 @default.
• W1971514240 cites W2001377273 @default.
• W1971514240 cites W2029853163 @default.
• W1971514240 cites W2041562703 @default.
• W1971514240 cites W2043407085 @default.
• W1971514240 cites W2046863715 @default.
• W1971514240 cites W2055708435 @default.
• W1971514240 cites W2056205598 @default.
• W1971514240 cites W2063832829 @default.
• W1971514240 cites W2074765346 @default.
• W1971514240 cites W2151611531 @default.
• W1971514240 cites W4232713821 @default.
• W1971514240 doi "https://doi.org/10.1021/jp077189m" @default.
• W1971514240 hasPublicationYear "2008" @default.
• W1971514240 type Work @default.
• W1971514240 sameAs 1971514240 @default.
• W1971514240 citedByCount "23" @default.
• W1971514240 countsByYear W19715142402012 @default.
• W1971514240 countsByYear W19715142402014 @default.
• W1971514240 countsByYear W19715142402015 @default.
• W1971514240 countsByYear W19715142402016 @default.
• W1971514240 countsByYear W19715142402020 @default.
• W1971514240 countsByYear W19715142402022 @default.
• W1971514240 countsByYear W19715142402023 @default.
• W1971514240 crossrefType "journal-article" @default.
• W1971514240 hasAuthorship W1971514240A5008370598 @default.
• W1971514240 hasAuthorship W1971514240A5019639436 @default.
• W1971514240 hasAuthorship W1971514240A5039292363 @default.
• W1971514240 hasAuthorship W1971514240A5045720453 @default.
• W1971514240 hasBestOaLocation W19715142402 @default.
• W1971514240 hasConcept C120665830 @default.
• W1971514240 hasConcept C121332964 @default.
• W1971514240 hasConcept C127413603 @default.
• W1971514240 hasConcept C131888329 @default.
• W1971514240 hasConcept C139719470 @default.
• W1971514240 hasConcept C147789679 @default.
• W1971514240 hasConcept C148898269 @default.
• W1971514240 hasConcept C150394285 @default.
• W1971514240 hasConcept C155672457 @default.
• W1971514240 hasConcept C159467904 @default.
• W1971514240 hasConcept C162324750 @default.
• W1971514240 hasConcept C171250308 @default.
• W1971514240 hasConcept C185592680 @default.
• W1971514240 hasConcept C191486275 @default.
• W1971514240 hasConcept C192562407 @default.
• W1971514240 hasConcept C42360764 @default.
• W1971514240 hasConcept C49271019 @default.
• W1971514240 hasConcept C62520636 @default.
• W1971514240 hasConcept C97355855 @default.
• W1971514240 hasConceptScore W1971514240C120665830 @default.
• W1971514240 hasConceptScore W1971514240C121332964 @default.
• W1971514240 hasConceptScore W1971514240C127413603 @default.
• W1971514240 hasConceptScore W1971514240C131888329 @default.
• W1971514240 hasConceptScore W1971514240C139719470 @default.
• W1971514240 hasConceptScore W1971514240C147789679 @default.
• W1971514240 hasConceptScore W1971514240C148898269 @default.
• W1971514240 hasConceptScore W1971514240C150394285 @default.
• W1971514240 hasConceptScore W1971514240C155672457 @default.
• W1971514240 hasConceptScore W1971514240C159467904 @default.
• W1971514240 hasConceptScore W1971514240C162324750 @default.
• W1971514240 hasConceptScore W1971514240C171250308 @default.
• W1971514240 hasConceptScore W1971514240C185592680 @default.
• W1971514240 hasConceptScore W1971514240C191486275 @default.
• W1971514240 hasConceptScore W1971514240C192562407 @default.
• W1971514240 hasConceptScore W1971514240C42360764 @default.
• W1971514240 hasConceptScore W1971514240C49271019 @default.
• W1971514240 hasConceptScore W1971514240C62520636 @default.
• W1971514240 hasConceptScore W1971514240C97355855 @default.
• W1971514240 hasIssue "13" @default.
• W1971514240 hasLocation W19715142401 @default.
• W1971514240 hasLocation W19715142402 @default.
• W1971514240 hasOpenAccess W1971514240 @default.
• W1971514240 hasPrimaryLocation W19715142401 @default.
• W1971514240 hasRelatedWork W1974078421 @default.
• W1971514240 hasRelatedWork W2093651284 @default.
• W1971514240 hasRelatedWork W2348837818 @default.
• W1971514240 hasRelatedWork W2369935614 @default.
• W1971514240 hasRelatedWork W2375620002 @default.
• W1971514240 hasRelatedWork W2378981175 @default.
• W1971514240 hasRelatedWork W2391638434 @default.
• W1971514240 hasRelatedWork W2748952813 @default.
• W1971514240 hasRelatedWork W2899084033 @default.
• W1971514240 hasRelatedWork W2522581513 @default.
• W1971514240 hasVolume "112" @default.
• W1971514240 isParatext "false" @default.

• next