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- W1971552425 abstract "For coupling of acetal-glycosides 3 and 4 of cytotoxic aldehydes with biopolymers for the selective treatment of cancer, acetals of type 5 or 6, which bear a carboxylic ester function or an acylated amino group in the alcohol moiety, were prepared by reaction of aldehydes 7a–d and the trimethylsilyl ethers 8a–d in the presence of a catalytic amount of trimethylsilyl trifluoromethanesulfonate.Synthese von funktionalisierten Acetalen zur Kupplung mit monoclonalen Antikorpern und anderen BiopolymerenIm Rahmen von Untersuchungen zur Entwicklung selektiver Cytostatika fur die Tumortherapie wurden zur Synthese von Acetalglycosiden des Typs 3 und 4 cytotoxisch wirkender Aldehyde, die sich mit Biopolymeren verknupfen lassen, die funktionalisierten Acetale 5 und 6 mit einer Ester- bzw. einer acylgeschutzten Aminogruppe im Alkoholteil dargestellt. Die Synthese erfolgte durch Reaktion der Aldehyde 7a–d mit den Trimethylsilylethern 8a–d in Gegenwart katalytischer Mengen Trifluormethansulfonsaure-trimethylsilylester." @default.
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- W1971552425 date "1988-06-20" @default.
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- W1971552425 title "Glycosidation, IX. Synthesis of functionalised acetals for coupling with monoclonal antibodies and other biopolymers" @default.
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- W1971552425 doi "https://doi.org/10.1002/jlac.198819880612" @default.
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