Matches in SemOpenAlex for { <https://semopenalex.org/work/W1971567491> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W1971567491 endingPage "271" @default.
- W1971567491 startingPage "263" @default.
- W1971567491 abstract "The effects of various alkylammonium thiocyanates (ethyl, butyl, hexyl, and octyl) on aqueous solutions of polyvinylpyrrolidone (PVP) and poly(vinyl alcohol–acetate) copolymer (PVA-Ac) were studied and compared with the effects caused by the respective chlorides. Whereas the PVP solution was hardly affected by the chlorides, it was precipitated by n-octylammonium thiocyanate (OASCN) at dilute concentrations and dissolved at higher concentrations. On taking the effects of ammonium chloride and thiocyanate on the solubility of PVA-Ac as references, with increasing of alkyl chain length, alkylammonium chlorides raised the polymer solubility steadily; on the contrary, the thiocyanates at dilute concentrations, except for ethylammonium thiocyanate, lowered it, and OASCN at dilute concentrations, except for ethylammonium thiocyanate, lowered it, and OASCN at dilute concentrations was a particularly strong salting-out agent. The amount of binding of OASCN to the polymers in the precipitated systems was measured. The precipitation was attributed to ion-pair binding of OASCN to the polymers, and the mechanism was discussed in terms of the interaction between the water structure-breaking SCN− and the water structure-making hydrophobic groups." @default.
- W1971567491 created "2016-06-24" @default.
- W1971567491 creator A5077030559 @default.
- W1971567491 date "1970-01-01" @default.
- W1971567491 modified "2023-09-29" @default.
- W1971567491 title "Precipitation of some nonionic polymers by octylammonium thiocyanate" @default.
- W1971567491 cites W1821319931 @default.
- W1971567491 cites W1964797538 @default.
- W1971567491 cites W2005631179 @default.
- W1971567491 cites W2024196744 @default.
- W1971567491 cites W2025655630 @default.
- W1971567491 cites W2042061628 @default.
- W1971567491 cites W2050586809 @default.
- W1971567491 cites W2067775292 @default.
- W1971567491 cites W2071664391 @default.
- W1971567491 cites W2074033361 @default.
- W1971567491 cites W2096001549 @default.
- W1971567491 cites W2126744959 @default.
- W1971567491 cites W2166529234 @default.
- W1971567491 cites W2318727222 @default.
- W1971567491 cites W2321075591 @default.
- W1971567491 cites W2322523131 @default.
- W1971567491 cites W2334450858 @default.
- W1971567491 doi "https://doi.org/10.1002/pol.1970.150080124" @default.
- W1971567491 hasPublicationYear "1970" @default.
- W1971567491 type Work @default.
- W1971567491 sameAs 1971567491 @default.
- W1971567491 citedByCount "11" @default.
- W1971567491 crossrefType "journal-article" @default.
- W1971567491 hasAuthorship W1971567491A5077030559 @default.
- W1971567491 hasConcept C107054158 @default.
- W1971567491 hasConcept C121332964 @default.
- W1971567491 hasConcept C153294291 @default.
- W1971567491 hasConcept C155574463 @default.
- W1971567491 hasConcept C169490005 @default.
- W1971567491 hasConcept C178790620 @default.
- W1971567491 hasConcept C179104552 @default.
- W1971567491 hasConcept C184651966 @default.
- W1971567491 hasConcept C185592680 @default.
- W1971567491 hasConcept C188027245 @default.
- W1971567491 hasConcept C2775868237 @default.
- W1971567491 hasConcept C2776294642 @default.
- W1971567491 hasConcept C2776371256 @default.
- W1971567491 hasConcept C2778695967 @default.
- W1971567491 hasConcept C2780077769 @default.
- W1971567491 hasConcept C2780263894 @default.
- W1971567491 hasConcept C2780666587 @default.
- W1971567491 hasConcept C521977710 @default.
- W1971567491 hasConceptScore W1971567491C107054158 @default.
- W1971567491 hasConceptScore W1971567491C121332964 @default.
- W1971567491 hasConceptScore W1971567491C153294291 @default.
- W1971567491 hasConceptScore W1971567491C155574463 @default.
- W1971567491 hasConceptScore W1971567491C169490005 @default.
- W1971567491 hasConceptScore W1971567491C178790620 @default.
- W1971567491 hasConceptScore W1971567491C179104552 @default.
- W1971567491 hasConceptScore W1971567491C184651966 @default.
- W1971567491 hasConceptScore W1971567491C185592680 @default.
- W1971567491 hasConceptScore W1971567491C188027245 @default.
- W1971567491 hasConceptScore W1971567491C2775868237 @default.
- W1971567491 hasConceptScore W1971567491C2776294642 @default.
- W1971567491 hasConceptScore W1971567491C2776371256 @default.
- W1971567491 hasConceptScore W1971567491C2778695967 @default.
- W1971567491 hasConceptScore W1971567491C2780077769 @default.
- W1971567491 hasConceptScore W1971567491C2780263894 @default.
- W1971567491 hasConceptScore W1971567491C2780666587 @default.
- W1971567491 hasConceptScore W1971567491C521977710 @default.
- W1971567491 hasIssue "1" @default.
- W1971567491 hasLocation W19715674911 @default.
- W1971567491 hasOpenAccess W1971567491 @default.
- W1971567491 hasPrimaryLocation W19715674911 @default.
- W1971567491 hasRelatedWork W1971567491 @default.
- W1971567491 hasRelatedWork W1995814887 @default.
- W1971567491 hasRelatedWork W2005168630 @default.
- W1971567491 hasRelatedWork W2020051561 @default.
- W1971567491 hasRelatedWork W2066615805 @default.
- W1971567491 hasRelatedWork W2068046803 @default.
- W1971567491 hasRelatedWork W2087493711 @default.
- W1971567491 hasRelatedWork W2357884709 @default.
- W1971567491 hasRelatedWork W3093836737 @default.
- W1971567491 hasRelatedWork W4206624766 @default.
- W1971567491 hasVolume "8" @default.
- W1971567491 isParatext "false" @default.
- W1971567491 isRetracted "false" @default.
- W1971567491 magId "1971567491" @default.
- W1971567491 workType "article" @default.