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• W1971569897 abstract "57Fe Mössbauer spectra (300 and 4.2°K) have been determined for dioxidized [Fe(III)Fe(III)] biferrocenylene; a large quadrupole splitting (2.89 mm/sec at 300°K) was interpreted in terms of extensive delocalization of e2g electrons resultant from an FeFe bonding interaction. Mössbauer and electronic absorption spectra have also been determined for two mono-oxidized [1.1] ferrocenophanes. Temperature dependence is noted in the [Fe(II)Fe(III)] ferrocenophane Mössbauer spectra and is tentatively associated with a phase transition wherein the FeFe distance is changed to permit greater FeFe exchange interaction." @default.
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• W1971569897 date "1973-09-01" @default.
• W1971569897 modified "2023-10-16" @default.
• W1971569897 title "Mixed-valence ferrocene systems temperature dependence in the mössbauer spectra of [Fe(II)Fe(III) [1.1] ferrocenophanes" @default.
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• W1971569897 doi "https://doi.org/10.1016/0009-2614(73)80548-2" @default.
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