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- W1971588284 abstract "Abstract The distribution of product electronic states from the reactions M 2 + X → MX + M * for MX = KCl, KBr, and RbBr is re-examined from the information theoretic viewpoint, using a hierarchy of prior distributions. Good agreement with experimental line intensities is achieved using a surprisal linear in the fraction of the total energy in electronic excitation with a small “temperature-like” suprisal parameter (λ q ⪅ 0.4 for the most precise of these priors). The continuous rigid rotor harmonic oscillator (RRHO) prior is shown to produce equally good agreement (with λq ⪅ 1), thus providing a simple analytical expression for branching ratios between product electronic states." @default.
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- W1971588284 date "1977-04-01" @default.
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- W1971588284 title "On the product electronic state distribution in reactions of alkali dimers with halogen atoms" @default.
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- W1971588284 doi "https://doi.org/10.1016/0009-2614(77)85294-9" @default.
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