FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1971593721> ?p ?o ?g. }

• W1971593721 endingPage "4360" @default.
• W1971593721 startingPage "4351" @default.
• W1971593721 abstract "Multiphoton ionization of neat liquid D2O at room temperature (295 K) with 2-eV subpicosecond laser pulses is used to study the solvation of electrons in this medium. The set of 20 measured kinetic traces covers a wide range of probing wavelengths (450−1450 nm), which allows us to obtain a global picture of the spectral changes that accompany electron hydration. The construction of transient absorption spectra from a proper normalization of the kinetic traces confirms the well-known existence of two absorbing species, one weakly bound absorbing chiefly in the infrared and a strongly bound one whose spectrum at long times is that of the well-characterized hydrated electron. The transient spectra also reveal the occurrence of a stepwise transition between these two species as well as a concomitant continuous blue shift of the strongly bound electron−solvent configuration. A nonlinear fit performed simultaneously on all the data allows the estimation of the characteristic kinetic and spectral parameters of our previously proposed hybrid model of electron solvation when it is applied to D2O. The global fit closely matches the data for the 20 different probing wavelengths investigated. The electrons are found to get trapped in 0.16 ± 0.02 ps, whereas the stepwise transition and the continuous blue shift characteristic times are 0.41 ± 0.02 and 0.51 ± 0.03 ps, respectively. The extent in energy of the monoexponential blue shift of the strongly bound electron spectrum is 0.34 ± 0.02 eV, a value which is very similar to the one that was found for electron solvation in methanol. Finally, it is estimated that about 34% of the electrons get directly trapped into the strongly bound state." @default.
• W1971593721 created "2016-06-24" @default.
• W1971593721 creator A5002392369 @default.
• W1971593721 creator A5011971701 @default.
• W1971593721 creator A5067995013 @default.
• W1971593721 creator A5088509992 @default.
• W1971593721 date "1997-06-01" @default.
• W1971593721 modified "2023-10-18" @default.
• W1971593721 title "Observation of a Continuous Spectral Shift in the Solvation Kinetics of Electrons in Neat Liquid Deuterated Water" @default.
• W1971593721 cites W146320344 @default.
• W1971593721 cites W180392968 @default.
• W1971593721 cites W1963791150 @default.
• W1971593721 cites W1965096538 @default.
• W1971593721 cites W1968559446 @default.
• W1971593721 cites W1968838342 @default.
• W1971593721 cites W1969472842 @default.
• W1971593721 cites W1983613097 @default.
• W1971593721 cites W1990812493 @default.
• W1971593721 cites W1991177366 @default.
• W1971593721 cites W1992085139 @default.
• W1971593721 cites W1992142634 @default.
• W1971593721 cites W1994875061 @default.
• W1971593721 cites W1995512245 @default.
• W1971593721 cites W1996097909 @default.
• W1971593721 cites W1996441837 @default.
• W1971593721 cites W1998995503 @default.
• W1971593721 cites W2000372341 @default.
• W1971593721 cites W2000778715 @default.
• W1971593721 cites W2001375602 @default.
• W1971593721 cites W2002562019 @default.
• W1971593721 cites W2006467957 @default.
• W1971593721 cites W2008934769 @default.
• W1971593721 cites W2010772149 @default.
• W1971593721 cites W2013567882 @default.
• W1971593721 cites W2013911886 @default.
• W1971593721 cites W2014063669 @default.
• W1971593721 cites W2015736247 @default.
• W1971593721 cites W2017980221 @default.
• W1971593721 cites W2021973309 @default.
• W1971593721 cites W2022243104 @default.
• W1971593721 cites W2022277299 @default.
• W1971593721 cites W2023682703 @default.
• W1971593721 cites W2024456163 @default.
• W1971593721 cites W2026270682 @default.
• W1971593721 cites W2026941519 @default.
• W1971593721 cites W2027681017 @default.
• W1971593721 cites W2029163465 @default.
• W1971593721 cites W2031132031 @default.
• W1971593721 cites W2032744579 @default.
• W1971593721 cites W2033103448 @default.
• W1971593721 cites W2033178857 @default.
• W1971593721 cites W2035032177 @default.
• W1971593721 cites W2036189046 @default.
• W1971593721 cites W2036420549 @default.
• W1971593721 cites W2036788192 @default.
• W1971593721 cites W2040112197 @default.
• W1971593721 cites W2040685329 @default.
• W1971593721 cites W2042301884 @default.
• W1971593721 cites W2042849936 @default.
• W1971593721 cites W2051344598 @default.
• W1971593721 cites W2053318299 @default.
• W1971593721 cites W2053488315 @default.
• W1971593721 cites W2056873954 @default.
• W1971593721 cites W2058373851 @default.
• W1971593721 cites W2062503092 @default.
• W1971593721 cites W2065298212 @default.
• W1971593721 cites W2068086808 @default.
• W1971593721 cites W2071012557 @default.
• W1971593721 cites W2073655223 @default.
• W1971593721 cites W2074535838 @default.
• W1971593721 cites W2076572603 @default.
• W1971593721 cites W2076611240 @default.
• W1971593721 cites W2076838304 @default.
• W1971593721 cites W2084563394 @default.
• W1971593721 cites W2084871992 @default.
• W1971593721 cites W2085831702 @default.
• W1971593721 cites W2087181203 @default.
• W1971593721 cites W2089529023 @default.
• W1971593721 cites W2090338066 @default.
• W1971593721 cites W2090602662 @default.
• W1971593721 cites W2111046697 @default.
• W1971593721 cites W2111518657 @default.
• W1971593721 cites W2124891861 @default.
• W1971593721 cites W2137606538 @default.
• W1971593721 cites W2162133431 @default.
• W1971593721 cites W2253174043 @default.
• W1971593721 cites W2474390293 @default.
• W1971593721 cites W2523141155 @default.
• W1971593721 doi "https://doi.org/10.1021/jp970354l" @default.
• W1971593721 hasPublicationYear "1997" @default.
• W1971593721 type Work @default.
• W1971593721 sameAs 1971593721 @default.
• W1971593721 citedByCount "77" @default.
• W1971593721 countsByYear W19715937212012 @default.
• W1971593721 countsByYear W19715937212013 @default.
• W1971593721 countsByYear W19715937212014 @default.
• W1971593721 countsByYear W19715937212015 @default.
• W1971593721 countsByYear W19715937212016 @default.

• next