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- W1971685714 abstract "The tris(bipyrazine) ruthenium(II) complex forms a series of complexes containing [Ru(II/III)EDTA](2-/-) groups coordinated to the peripheral nitrogen atoms of the bipyrazine bridging ligand. These groups exhibit similar redox potentials (E(0) = 0.38 V vs. SHE) and a very weak electronic coupling through the central complex. When the peripheral Ru(III) groups are reduced to the Ru(II) state, strong charge-transfer bands appear at 490 and 670 nm and the stability constants increase by 7 orders of magnitude due to d(pi) -p(*)(pi) back-bonding interactions involving the peripheral ions and the bipyrazine ligand." @default.
- W1971685714 created "2016-06-24" @default.
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- W1971685714 date "1993-04-01" @default.
- W1971685714 modified "2023-09-27" @default.
- W1971685714 title "Equilibria and spectroelectrochemical studies on the formation of multibridged tris(bipyrazine) ruthenium(II) complexes with ruthenium—edta groups" @default.
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- W1971685714 doi "https://doi.org/10.1016/0039-9140(93)80010-o" @default.
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