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- W1971702020 abstract "The photoelectron emission cross section as a function of exciting photon energy of the emitter molecule in solution is assumed to be the same as that of a free molecule. The photoelectron emission yield spectra for solutions can then be obtained by simulation calculation using gas-phase UPS spectra. They are compared with the experimental spectra to give the conclusion that the threshold energy determined for solution of ferrocene or benzene exhibiting a narrow first band in UPS corresponds to the vertical ionization process, while that for alkylamine exhibiting a broad band in UPS corresponds to the average value of the energies for vertical and adiabatic process. Polarization energies of the solvent, acetonitrile, determined for these molecules are well predicted by the Born model." @default.
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- W1971702020 date "1986-01-01" @default.
- W1971702020 modified "2023-10-17" @default.
- W1971702020 title "Photoelectron emission spectra of butylamine, ferrocene and benzene solutions compared with simulated spectra using gas-phase UPS" @default.
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- W1971702020 doi "https://doi.org/10.1016/0368-2048(86)80041-x" @default.
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