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- W1971719482 abstract "Kinetic data for reactions of (P-en)Mo(CO)4 (P-en = ethylenediphosphine, H2PC2H4PH2) with phosphines and phosphites (L) in mesitylene solvent at 108–135° suggest three competing mechanisms, depending upon the Lewis base employed: a, rate-determining dissociation of CO; b, nucleophilic attack of L on the substrate and c, reversible dissociation of one end of the P-en ligand, followed by attack of L on the resulting five-coordinate intermediate. Of particular interest is the rate via path b for L = P(OC2H5)3 which can be compared to rates for analogous reactions of other cis-L2Mo(CO)4 substrates, and to that for the hexacarbonyl itself. Attack in (P-en)Mo(CO)4 occurs at a relatively slow rate, a result which is examined in terms of the nature of the interaction in the activated complex for these reactions." @default.
- W1971719482 created "2016-06-24" @default.
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- W1971719482 date "1972-01-01" @default.
- W1971719482 modified "2023-09-23" @default.
- W1971719482 title "Octahedral metal carbonyls. XXV. Kinetics and mechanism of reactions of (ethylenedisphosphine)tetracarbonylmolybdenum(0) with lewis bases" @default.
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- W1971719482 doi "https://doi.org/10.1016/s0020-1693(00)91846-2" @default.
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