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- W1971794103 abstract "Abstract The interaction of Cu(acac) 2 , Cu(ox) 2 , Cu(tox) 2 , Cu(dtc) 2 , and Cu(dtp) 2 with NO x (x = 1 or 2) is studied by EPR and electronic spectroscopy. It is found that weak reversible adducts are formed between Cu(dtc) 2 , Cu(dtp) 2 and Cu(tox) 2 and NO, while No 2 oxidizes the ligands in all complexes. The reaction of Cu(dtc) 2 with NO 2 proceeds through mixed-ligand complexes with the participation of NO − 3 . Cu(NO 3 ) 2 and disulphides from the ligands are proved as final products from Cu(dtc) 2 , Cu(dtp) 2 and Cu(tox) 2 . Free radicals from the ligands of iminoxy type are detected in the reactions of Cu(ox) 2 and Cu(acac) 2 with NO 2 ." @default.
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- W1971794103 date "1982-01-01" @default.
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- W1971794103 title "Studies on the intermolecular interactions of metal chelate complexes. I. spectroscopic study on the interaction of copper(II) chelate complexes with NOx" @default.
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- W1971794103 doi "https://doi.org/10.1016/s0020-1693(00)90248-2" @default.
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