Matches in SemOpenAlex for { <https://semopenalex.org/work/W1971798887> ?p ?o ?g. }
- W1971798887 endingPage "50" @default.
- W1971798887 startingPage "39" @default.
- W1971798887 abstract "Silica supported platinum-gold and platinum-copper catalysts prepared from organometallic cluster precursors were characterized with diffuse reflectance Fourier-transform spectroscopy (DRIFTS) of adsorbed CO. Because of the effects that dipole coupling of adsorbed carbon monoxide molecules can have on the infrared spectrum, coverage studies were employed to evaluate the interactions between CO and the catalyst surfaces. DRIFTS spectra of the catalysts prepared from bimetallic molecular cluster precursors showed significantly lower CO stretching frequencies relative to a traditionally prepared platinum catalyst. The lowering of the CO stretching frequency may be the result of the formation of unique alloys and particle morphologies. In the case of the catalyst prepared from the platinum-copper cluster, two peaks were identified in the PtCO stretching region, one of which is postulated to be a bridging or semi-bridging mode between Pt and Cu. Infrared spectroscopy results are also discussed in relation to kinetic data from the n-hexane conversion reaction. Differences in catalyst activities and selectivities are concluded to be primarily due to geometric (i.e. structural or morphological) effects." @default.
- W1971798887 created "2016-06-24" @default.
- W1971798887 creator A5089248364 @default.
- W1971798887 creator A5091437984 @default.
- W1971798887 date "2001-02-01" @default.
- W1971798887 modified "2023-10-16" @default.
- W1971798887 title "DRIFTS studies of carbon monoxide coverage on highly dispersed bimetallic Pt-Cu and Pt-Au catalysts" @default.
- W1971798887 cites W147930249 @default.
- W1971798887 cites W1480045658 @default.
- W1971798887 cites W1485514408 @default.
- W1971798887 cites W1522951955 @default.
- W1971798887 cites W1566260982 @default.
- W1971798887 cites W1605013397 @default.
- W1971798887 cites W1608134834 @default.
- W1971798887 cites W181018557 @default.
- W1971798887 cites W1963881797 @default.
- W1971798887 cites W1965792962 @default.
- W1971798887 cites W1974980704 @default.
- W1971798887 cites W1975521446 @default.
- W1971798887 cites W1976389266 @default.
- W1971798887 cites W1980334025 @default.
- W1971798887 cites W1980716863 @default.
- W1971798887 cites W1981322223 @default.
- W1971798887 cites W1982935551 @default.
- W1971798887 cites W1993154502 @default.
- W1971798887 cites W1995361742 @default.
- W1971798887 cites W1996526486 @default.
- W1971798887 cites W2000539007 @default.
- W1971798887 cites W2003508754 @default.
- W1971798887 cites W2005940960 @default.
- W1971798887 cites W2021204419 @default.
- W1971798887 cites W2021660957 @default.
- W1971798887 cites W2026374628 @default.
- W1971798887 cites W2032340427 @default.
- W1971798887 cites W2035706324 @default.
- W1971798887 cites W2042003689 @default.
- W1971798887 cites W2046117358 @default.
- W1971798887 cites W2047622922 @default.
- W1971798887 cites W2051540446 @default.
- W1971798887 cites W2052545593 @default.
- W1971798887 cites W2056758245 @default.
- W1971798887 cites W2059544074 @default.
- W1971798887 cites W2061020224 @default.
- W1971798887 cites W2064557488 @default.
- W1971798887 cites W2072988514 @default.
- W1971798887 cites W2073203435 @default.
- W1971798887 cites W2074000604 @default.
- W1971798887 cites W2074718560 @default.
- W1971798887 cites W2079754166 @default.
- W1971798887 cites W2085063199 @default.
- W1971798887 cites W2085741101 @default.
- W1971798887 cites W2090127748 @default.
- W1971798887 cites W2090521575 @default.
- W1971798887 cites W2092393026 @default.
- W1971798887 cites W2093941029 @default.
- W1971798887 cites W2195749374 @default.
- W1971798887 cites W2204332160 @default.
- W1971798887 cites W2952247962 @default.
- W1971798887 cites W31961846 @default.
- W1971798887 cites W4246151265 @default.
- W1971798887 doi "https://doi.org/10.1016/s0920-5861(00)00543-5" @default.
- W1971798887 hasPublicationYear "2001" @default.
- W1971798887 type Work @default.
- W1971798887 sameAs 1971798887 @default.
- W1971798887 citedByCount "47" @default.
- W1971798887 countsByYear W19717988872012 @default.
- W1971798887 countsByYear W19717988872013 @default.
- W1971798887 countsByYear W19717988872014 @default.
- W1971798887 countsByYear W19717988872017 @default.
- W1971798887 countsByYear W19717988872018 @default.
- W1971798887 countsByYear W19717988872020 @default.
- W1971798887 countsByYear W19717988872021 @default.
- W1971798887 countsByYear W19717988872022 @default.
- W1971798887 countsByYear W19717988872023 @default.
- W1971798887 crossrefType "journal-article" @default.
- W1971798887 hasAuthorship W1971798887A5089248364 @default.
- W1971798887 hasAuthorship W1971798887A5091437984 @default.
- W1971798887 hasConcept C147789679 @default.
- W1971798887 hasConcept C150394285 @default.
- W1971798887 hasConcept C153642686 @default.
- W1971798887 hasConcept C161790260 @default.
- W1971798887 hasConcept C175583648 @default.
- W1971798887 hasConcept C178790620 @default.
- W1971798887 hasConcept C179104552 @default.
- W1971798887 hasConcept C185592680 @default.
- W1971798887 hasConcept C43411465 @default.
- W1971798887 hasConcept C512735826 @default.
- W1971798887 hasConcept C518104683 @default.
- W1971798887 hasConcept C544778455 @default.
- W1971798887 hasConceptScore W1971798887C147789679 @default.
- W1971798887 hasConceptScore W1971798887C150394285 @default.
- W1971798887 hasConceptScore W1971798887C153642686 @default.
- W1971798887 hasConceptScore W1971798887C161790260 @default.
- W1971798887 hasConceptScore W1971798887C175583648 @default.
- W1971798887 hasConceptScore W1971798887C178790620 @default.
- W1971798887 hasConceptScore W1971798887C179104552 @default.
- W1971798887 hasConceptScore W1971798887C185592680 @default.
- W1971798887 hasConceptScore W1971798887C43411465 @default.