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- W1971836475 abstract "We use femtosecond infrared spectroscopy to study the aqueous protonation dynamics of cyanate, OCN−, using a photoacid, 2-naphthol-6,8-disulfonate (2N-6,8S) excited by a 60-fs pulse tuned at 336 nm. The transient response in the spectral range of the cyano-stretching vibrational marker modes of cyanic acid, HOCN, and isocyanic acid, HNCO, reveals how much of both reaction products are formed at early delay times, and whether the on-contact reactive complex between 2N-6,8S and OCN− has a well-defined structure. Using the Szabo-Collins-Kimball approach to describe bimolecular reaction dynamics subject to the Debye-von Smoluchowski diffusional motions, an on-contact proton transfer reaction rate is derived that follows the correlation between free energy and reaction rates found for a large class of aqueous proton transfer of photoacid dissociation and photoacid-base neutralization reactions." @default.
- W1971836475 created "2016-06-24" @default.
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- W1971836475 date "2009-07-01" @default.
- W1971836475 modified "2023-10-02" @default.
- W1971836475 title "Ultrafast Protonation of Cyanate Anion in Aqueous Solution" @default.
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- W1971836475 doi "https://doi.org/10.1560/ijc.49.2.217" @default.
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