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• W1971846736 abstract "Tetraphenyl iron(III) and manganese(III) porphyrin chloride (FeTPPCl and MnTPPCl) are studied by electrospray ionization tandem mass spectrometry (ESI/MS/MS). Removal of the chloride counter ion from these salts results in intense [FeTPP]+ and [MnTPP]+ ions that lose hydrogen and peripheral phenyl rings upon multi-collision-induced dissociation (CID). Dissociation pathways are probed as a function of collision-offset voltage with onset measurements. Onset voltages generally are higher for [MnTPP]+. While primary losses of benzene, biphenyl and hydrogen occur concomitantly at low collision voltages, losses of hydrogen from the secondary and higher-order ions occur at higher collision voltages. Comparisons are made with previous measurements using surface-induced dissociation, photodissociation and electron impact." @default.
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• W1971846736 date "2009-01-01" @default.
• W1971846736 modified "2023-10-04" @default.
• W1971846736 title "Collision-induced dissociation of tetraphenyl iron and manganese porphyrin ions by electrospray ionization mass spectrometry" @default.
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• W1971846736 doi "https://doi.org/10.1016/j.ijms.2008.10.018" @default.
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