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- W1971855984 abstract "Complexes of di-π-cyclopentadienyltitanium chloride (Cp2TiCl) with the trichlorides of Group III elements, having the bridged structure show EPR hyperfine interaction of the unpaired electron of the TiIII with the magnetic nuclei of the Group III elements. The hyperfine pattern of 115In(I = 92) is reported for the first time. From the isotropic coupling with 11B, 27Al, 69Ga, 71Ga, 115In, the unpaired spin density in the relevant s-orbitals of the Group III elements is estimated. The following series is deduced for the Lewis acidity (electron acceptor ability) of the halides: GaCl3 > BCl3 > AlCl3 > InCl3. The results are considered in the light of published information, and chemical evidence is advanced for the strong acid character of GaCl3." @default.
- W1971855984 created "2016-06-24" @default.
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- W1971855984 date "1969-04-01" @default.
- W1971855984 modified "2023-09-27" @default.
- W1971855984 title "Electron proton resonance of transition metal complexes VII. Epr-approach to lewis acidity of group III halides" @default.
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- W1971855984 doi "https://doi.org/10.1016/s0022-328x(00)88038-9" @default.
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