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• W1971872623 abstract "Dinuclear and cubane-shaped lanthanide cluster complexes containing EuIII)and TbIII were synthesized by step-by-step construction using p-tert-butylsulfonylcalix[4]arene as a cluster-forming ligand. The sulfonylcalixarene adopts a pinched-cone conformation in the dinuclear complexes and a cone conformation in the cubane complexes. Because the calixarene has a large pi-conjugate system expanding over the entire molecule, it behaves as a good antenna chromophore for UV and near-UV light, and a slight conformational change of the calixarene (from cone to pinched-cone and vice versa) has an effect on the energy levels of excited S1 and T1 states. As a result, selectivity is observed in the luminescent properties of dinuclear and cubane-shaped systems of EuIII and TbIII." @default.
• W1971872623 created "2016-06-24" @default.
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• W1971872623 date "2006-05-25" @default.
• W1971872623 modified "2023-10-13" @default.
• W1971872623 title "Conformation-Controlled Luminescent Properties of Lanthanide Clusters Containing <i>p-tert</i>-Butylsulfonylcalix[4]arene" @default.
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• W1971872623 doi "https://doi.org/10.1021/ic060397t" @default.
• W1971872623 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16780304" @default.
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