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- W1971918619 endingPage "13092" @default.
- W1971918619 startingPage "13092" @default.
- W1971918619 abstract "The planar platinum(II) complex [Pt(Me3SiC≡CbpyC≡CSiMe3)(C≡CC6H4Et-4)2] (1) with 5,5-bis(trimethylsilylethynyl)-2,2'-bipyridine was prepared and characterized. Solid-state 1 exhibits unusual, selective and reversible luminescence vapochromism to CH3CN and ClCH2CN vapors, which is useful for the detection of these hazardous vapors. A vapochromic cycle was monitored by dynamic variations in emission spectra and X-ray diffraction (XRD) patterns. Both X-ray crystallographic and density functional theory studies suggest that the vapochromic and vapoluminescent behavior of 1 are induced by the variation in the intermolecular Pt-Pt interactions." @default.
- W1971918619 created "2016-06-24" @default.
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- W1971918619 date "2013-01-01" @default.
- W1971918619 modified "2023-09-23" @default.
- W1971918619 title "A new sensor for detection of CH3CN and ClCH2CN vapors based on vapoluminescent platinum(ii) complex" @default.
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- W1971918619 doi "https://doi.org/10.1039/c3dt51397a" @default.
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