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- W1971928286 abstract "Abstract Unexpected differences in the aluminium bromide-catalyzed rearrangement behaviour of 1,2- endo -trimethylenenorbornane ( 1 ) and its 1,2- exo -isomer ( 2 ) are interpreted. Isotopic labelling studies indicate that reversible abstraction of the tertiary 2- endo hydride in 2 does not occur. Instead, rearrangement to 6 is favored. The label scrambling in the final product, adamantane ( 8 ), is attributed to degenerate isomerization in the proto-adamantyl precursor, 7 ." @default.
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- W1971928286 date "1981-01-01" @default.
- W1971928286 modified "2023-09-25" @default.
- W1971928286 title "Adamantane rearrangement mechanisms. 1,2-trimethylenenorbornanes" @default.
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- W1971928286 doi "https://doi.org/10.1016/s0040-4039(01)90361-2" @default.
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