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- W1971930072 abstract "The interaction between 1,3,5-trinitrobenzene and sulfite ion has been studied by spectrophotometry. A new absorption band which cannot be ascribed to either of the components was observed at 462 mμ. From quantitative measurements of this band at various concentrations and temperatures, it was found that sulfite ion and 1,3,5-trinitrobenzene form a stable 1:1 complex with ΔH 0 of − 4.00 ± 0.14 kcal mole −1 and ΔS 0 of − 2.26 ± 0.50 e.u. (entropy units). At 25.3°C, the formation constant (K) for complex formation and the molar extinction coefficient (ϵ) of the complex are 2.67 × 10 2 l mole −1 and 2.35 × 10 4 l mole −1 cm −1 respectively. Values of K and ϵ for the complex formation reactions of sulfite ion with 2,4,6-trinitrotoluene and 2,4,6-trinitrobenzaldehyde are also reported." @default.
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- W1971930072 date "1967-01-15" @default.
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- W1971930072 title "Sulfite complexes of 1,3,5-trinitrobenzene and related compounds" @default.
- W1971930072 doi "https://doi.org/10.1139/v67-034" @default.
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