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• W1971945791 abstract "A simple but efficient method has been first developed for the solution preparation of CrOx as anode buffer layer for polymer photovoltaic cells. The chromium acetylacetonate precursor can be transformed into CrOx upon thermal annealing at ∼60 °C, followed by ultraviolet-ozone treatment. The leakage current of the device with the CrOx anode buffer layer was decreased, and short-circuit current density (Jsc) was significantly increased in comparison with the device with the traditional poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate) (PEDOT:PSS) buffer layer. By analyzing the current density–voltage characteristics of the device, it is found that the CrOx anode buffer layer can simultaneously decrease the series resistance and increase the parallel resistance of the device, in comparison with the device with PEDOT:PSS anode buffer layer. For the cells based on poly(3-hexylthiophene) (P3HT) as donor and (6,6)-phenyl-C61-butyric acid methyl ester (PCBM) as acceptor, the power conversion efficiency (PCE) can be improved from 3.71% (with PEDOT:PSS buffer) to 4.27% via introduction of CrOx buffer layer. The PCE of the device based on P3HT as donor and indene-C60-bisadduct (ICBA) as acceptor with CrOx anode buffer layer was further increased from 6.08 (with PEDOT:PSS buffer) to 6.55%. The results indicate that CrOx is a promising anode buffer layer for efficient and stable polymer solar cells." @default.
• W1971945791 created "2016-06-24" @default.
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• W1971945791 date "2014-04-25" @default.
• W1971945791 modified "2023-10-17" @default.
• W1971945791 title "Solution-Processed and Low-Temperature Annealed CrO_<i>x</i> as Anode Buffer Layer for Efficient Polymer Solar Cells" @default.
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• W1971945791 doi "https://doi.org/10.1021/jp411675t" @default.
• W1971945791 hasPublicationYear "2014" @default.
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