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- W1971960989 abstract "The ring inversion of some 5,5-dimethyl-1, 3-dioxans bearing spiro substituents (cyclobutane, cyclopentane and cyclohexane) at the 2-position has been investigated by high resolution n.m.r. using the total line-shape method. The activation parameters for this process have been determined and the importance of steric syn-axial interactions in determining the height of the barrier to inversion has been confirmed. Large negative values of ΔS≠ for the inversion process were obtained in two cases." @default.
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- W1971960989 date "1970-01-01" @default.
- W1971960989 modified "2023-09-24" @default.
- W1971960989 title "Ring inversion of some 5,5-dimethyl-2-spiro-1,3-dioxans" @default.
- W1971960989 doi "https://doi.org/10.1039/tf9706602948" @default.
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