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- W1971970354 abstract "[reaction: see text] The Diels-Alder reaction of some substituted 5,6,7,8-tetrahydro-2H-1-benzopyran-2-ones (1a-f) with N-substituted maleimides (2a-c) leading to fused isoindole derivatives (5a-n, 7) or, in a few cases, to bridged double cycloadducts (fused bicyclo[2.2.2]octene derivatives) (6a-f) is presented. When X = CO, the first efficient, substituent-driven aromatization of an intermediary-formed cycloadduct was observed, resulting in substituted benz[e]isoindoles (5a-k). The same type of aromatization can also be achieved in an unprecedented catalysis with Rh/C." @default.
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- W1971970354 date "2003-07-08" @default.
- W1971970354 modified "2023-10-16" @default.
- W1971970354 title "Diels−Alder Reactions of Fused Pyran-2-ones with Maleimides: Efficient Syntheses of Benz[<i>e</i>]isoindoles and Related Systems" @default.
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- W1971970354 doi "https://doi.org/10.1021/ol034852q" @default.
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