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- W1972031984 abstract "The dark green crystalline [ZrCp″2(CO)2] (Cp″ = η-C5H3(SiMe3)2), (I) (δ(13CO) 264 ppm), was prepared by reduction from [ZrCp″2Cl2] and either CO (using NaHg, MgHgCl2, or Li2 [COT]) or CO2(NaHg) in high (CO) to moderate (CO2) yield; the NaHg/CO procedure was much more effective than for Zr analogues having η-C5H5 or η-C5H4(SiMe3) ligands; the carbonyl complex I is a convenient precursor to CO-free derivatives obtained either by oxidative addition or ligand displacement." @default.
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- W1972031984 date "1984-09-01" @default.
- W1972031984 modified "2023-09-23" @default.
- W1972031984 title "High yield syntheses and characterisation of a new zirconocene(II) dicarbonyl (Zr[η-C5H3(SiMe3)2]2(CO)2], a convenient precursor to various zirconocene(II or IV) complexes" @default.
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- W1972031984 doi "https://doi.org/10.1016/0022-328x(84)80488-x" @default.
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