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- W1972037291 abstract "[formula: see text] The complexation between N,N'-dibenzyl(m-xylylene)diammonium bis(hexafluorophosphate) (2) and bis(m-phenylene)-32-crown-10 (5) was shown to occur in solution by nuclear magnetic resonance with 1:1 stoichiometry and a Ka value of 189 +/- 19 M-1. A crystal structure of 2:5 revealed a unique 1:1 exo or cradled barbell complex, instead of the expected pseudorotaxane. This unexpected result illustrates that caution be used in interpreting the results from these types of complexes in the solution and gas phases on the basis of crystal structures." @default.
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- W1972037291 date "1999-05-24" @default.
- W1972037291 modified "2023-10-05" @default.
- W1972037291 title "Unique “Cradled Barbell” Complex between a Secondary Diammonium Ion and Bis(<i>m</i>-phenylene)-32-crown-10" @default.
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- W1972037291 doi "https://doi.org/10.1021/ol9905708" @default.
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