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- W1972040268 abstract "Abstract Two acyclic Schiff-base ligands, bis-5,5′-(1,3-propanediyldiimino)-2,2-dimethyl-4-hexene-3-one and bis-5,5′-(1,3-ethanediyldiimino)-2,2-dimethyl-4-hexene-3-one, were used to complex homoleptic triethylaluminum and tris[bis(trimethylsilyl)amino]aluminum, respectively. The acid–base reactions proceeded in excellent yields with elimination of ethane or bis(trimethylsilyl)amine during in situ deprotonation of the protio Schiff-base. The colorless aluminum complexes crystallized from n-pentane and were characterized by standard methods including single crystal X-ray diffraction. Polymerization of racemic lactide, with addition of alcohol, yielded PLA with narrow polydispersities but low molecular weights." @default.
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- W1972040268 date "2007-08-01" @default.
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- W1972040268 title "Synthesis and structural characterization of two five coordinate aluminum alkyl and bis(trimethylsilyl)amino complexes bearing acyclic tetradentate Schiff bases" @default.
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- W1972040268 doi "https://doi.org/10.1016/j.poly.2007.03.008" @default.
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